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Author:

Chen, Hao (Chen, Hao.) | Liu, Weiqiang (Liu, Weiqiang.) | Yang, Tianyuan (Yang, Tianyuan.) | Guo, Zizhen (Guo, Zizhen.) | Xu, Xiaochang (Xu, Xiaochang.) | Li, Yuqing (Li, Yuqing.) | Zhang, Hongguo (Zhang, Hongguo.) | Yue, Ming (Yue, Ming.)

Indexed by:

EI Scopus SCIE

Abstract:

Currently, the continued high prices of the heavy rare earth (HRE) elements Dy and Tb are prompting an exploration of the development of HRE-free high-performance 2:14:1-type permanent magnets. In this paper, a high maximum energy product of 44.04 MGOe at room temperature (RT) was obtained while maintaining a coercivity greater than 20 kOe in HRE-free Pr-Fe-B sintered magnets through microstructural regulation, which reached an equivalent to the commercially 45SH level. The Pr-Fe-B sintered magnet possesses excellent magnetic properties at low temperatures, and its remanence and coercivity increased to 14.75 kG and 75.01 kOe at −170 °C, respectively. Microstructure analysis indicated that the fine and uniform columnar crystals in the strip-casting (SC) alloys provided conditions for the preparation of fine-grained jet milling (JM) powders and sintered magnets. After annealing, the continuous grain boundary (GB) layers and the fine grain size of 2.80 μm ensured high coercivity. Meanwhile, the reduction of microcracking at the GB helps densification and the improvement of c-axis alignment ensured high remanence. The above exploration of microstructural regulation throughout the metallurgical process can provide meaningful guidance for the development of HRE-free Pr-Fe-B sintered magnets with high performance. © 2022 Elsevier B.V.

Keyword:

Iron compounds Rare earths Grain refinement Remanence Sintering Grain boundaries Grain size and shape Coercive force Magnets Neodymium alloys Microstructure

Author Community:

  • [ 1 ] [Chen, Hao]Faculty of Materials and Manufacturing, Key Laboratory of Advanced Functional Materials, Ministry of Education of China, Beijing University of Technology, Beijing; 100124, China
  • [ 2 ] [Liu, Weiqiang]Faculty of Materials and Manufacturing, Key Laboratory of Advanced Functional Materials, Ministry of Education of China, Beijing University of Technology, Beijing; 100124, China
  • [ 3 ] [Yang, Tianyuan]Faculty of Materials and Manufacturing, Key Laboratory of Advanced Functional Materials, Ministry of Education of China, Beijing University of Technology, Beijing; 100124, China
  • [ 4 ] [Guo, Zizhen]Faculty of Materials and Manufacturing, Key Laboratory of Advanced Functional Materials, Ministry of Education of China, Beijing University of Technology, Beijing; 100124, China
  • [ 5 ] [Xu, Xiaochang]Faculty of Materials and Manufacturing, Key Laboratory of Advanced Functional Materials, Ministry of Education of China, Beijing University of Technology, Beijing; 100124, China
  • [ 6 ] [Li, Yuqing]Faculty of Materials and Manufacturing, Key Laboratory of Advanced Functional Materials, Ministry of Education of China, Beijing University of Technology, Beijing; 100124, China
  • [ 7 ] [Zhang, Hongguo]Faculty of Materials and Manufacturing, Key Laboratory of Advanced Functional Materials, Ministry of Education of China, Beijing University of Technology, Beijing; 100124, China
  • [ 8 ] [Yue, Ming]Faculty of Materials and Manufacturing, Key Laboratory of Advanced Functional Materials, Ministry of Education of China, Beijing University of Technology, Beijing; 100124, China

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Source :

Journal of Magnetism and Magnetic Materials

ISSN: 0304-8853

Year: 2022

Volume: 563

2 . 7

JCR@2022

2 . 7 0 0

JCR@2022

ESI Discipline: PHYSICS;

ESI HC Threshold:41

JCR Journal Grade:3

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 4

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 11

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