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Author:

Liu, Huan (Liu, Huan.) | Wu, Tianhao (Wu, Tianhao.) | Zhang, Liqiang (Zhang, Liqiang.) | Wang, Xin (Wang, Xin.) | Li, Haifeng (Li, Haifeng.) | Liu, Shiqi (Liu, Shiqi.) | Zhang, Qi (Zhang, Qi.) | Zhang, Xu (Zhang, Xu.) | Yu, Haijun (Yu, Haijun.) (Scholars:尉海军)

Indexed by:

EI Scopus SCIE

Abstract:

Germanium (Ge)-based materials can serve as promising anode candidates for high-energy lithium ion batteries (LIBs). However, the rapid capacity decay caused by huge volume expansion severely retards their application. Herein, we report a facile and controllable synthesis of Ge nanowire anode materials through molten salt electrolysis. The optimal Ge nanowires can deliver a capacity of 1058.9 mAh g(-1) at 300 mA g(-1) and a capacity above 602.5 mAh g(-1) at 3000 mA g(-1) for 900 cycles. By in situ transmission electron microscopy and in situ X-ray diffraction, the multiple-step phase transformation and good structural reversibility of the Ge nanowires during charge/discharge are elucidated. When coupled with a lithium-rich Li(1.2)Mn(0.56)7Ni(0.167)Co(0.06)7O(2) cathode in a full battery, the Ge nanowire anode leads to a relatively stable capacity with a retention of 84.5% over 100 cycles. This research highlights the significance of molten-salt electrolysis for the synthesis of alloy-type anode materials toward high-energy LIBs.

Keyword:

Ge nanowires Li-ion battery anode materials in situ TEM molten-salt electrolysis

Author Community:

  • [ 1 ] [Liu, Huan]Beijing Univ Technol, Inst Adv Battery Mat & Devices, Fac Mat & Mfg, Minist Educ, Beijing 100124, Peoples R China
  • [ 2 ] [Wu, Tianhao]Beijing Univ Technol, Inst Adv Battery Mat & Devices, Fac Mat & Mfg, Minist Educ, Beijing 100124, Peoples R China
  • [ 3 ] [Li, Haifeng]Beijing Univ Technol, Inst Adv Battery Mat & Devices, Fac Mat & Mfg, Minist Educ, Beijing 100124, Peoples R China
  • [ 4 ] [Liu, Shiqi]Beijing Univ Technol, Inst Adv Battery Mat & Devices, Fac Mat & Mfg, Minist Educ, Beijing 100124, Peoples R China
  • [ 5 ] [Zhang, Qi]Beijing Univ Technol, Inst Adv Battery Mat & Devices, Fac Mat & Mfg, Minist Educ, Beijing 100124, Peoples R China
  • [ 6 ] [Zhang, Xu]Beijing Univ Technol, Inst Adv Battery Mat & Devices, Fac Mat & Mfg, Minist Educ, Beijing 100124, Peoples R China
  • [ 7 ] [Yu, Haijun]Beijing Univ Technol, Inst Adv Battery Mat & Devices, Fac Mat & Mfg, Minist Educ, Beijing 100124, Peoples R China
  • [ 8 ] [Liu, Huan]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 9 ] [Wu, Tianhao]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 10 ] [Li, Haifeng]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 11 ] [Liu, Shiqi]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 12 ] [Zhang, Qi]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 13 ] [Zhang, Xu]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 14 ] [Yu, Haijun]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 15 ] [Zhang, Liqiang]Yanshan Univ, Clean Nano Energy Ctr, State Key Lab Metastable Mat Sci & Technol, Qinhuangdao 066004, Peoples R China
  • [ 16 ] [Wang, Xin]China Univ Petr, Dept Mat Sci & Engn, Beijing 102249, Changping, Peoples R China

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Source :

ACS NANO

ISSN: 1936-0851

Year: 2022

Issue: 9

Volume: 16

Page: 14402-14411

1 7 . 1

JCR@2022

1 7 . 1 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:53

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 18

SCOPUS Cited Count: 19

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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