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Author:

Gao, Wen-Bo (Gao, Wen-Bo.) | Li, Yong-Hui (Li, Yong-Hui.) | He, Ji-Yu (He, Ji-Yu.) | Yang, Rong-Jie (Yang, Rong-Jie.)

Indexed by:

EI Scopus PKU CSCD

Abstract:

In order to determine the storage stability of propargyl-terminated polybutadiene (PTPB) at room temperature, the storage stability of PTPB at room temperature(15-30), 5 and -10 was investigated by tracking test. The chemical structures and properties of PTPB stored at different temperatures and times were characterized by 13C-NMR, FTIR, TG, GPC and viscosity tests. The PTPB elastomers were prepared from the stored PTPB prepolymer and azido-glycidyl ether (GAP) and the properties of elastomers were characterized by FT-IR, DMA and mechanical tests. The results show that the PTPB stored at room temperature for four months has the same chemical structure and properties as that of PTPB stored at 5 and -10, no polymerization, cross-linking, oxidation and other reactions have taken place, and the viscosity has not changed. After storing for four months under three different temperatures, the molecular structure, dynamic mechanics performance, mechanics performance at room temperature of PTPB elastomers made from stored PTPB are also consistent. Therefore, PTPB can be stored stably at room temperature. © 2019, Editorial Board of Journal of Explosives & Propellants. All right reserved.

Keyword:

Structure (composition) Chemical analysis Stability Crosslinking Plastics Elastomers Viscosity Polybutadienes Monomers

Author Community:

  • [ 1 ] [Gao, Wen-Bo]School of Materials, Beijing University of Technology, Beijing; 100081, China
  • [ 2 ] [Li, Yong-Hui]School of Materials, Beijing University of Technology, Beijing; 100081, China
  • [ 3 ] [He, Ji-Yu]School of Materials, Beijing University of Technology, Beijing; 100081, China
  • [ 4 ] [Yang, Rong-Jie]School of Materials, Beijing University of Technology, Beijing; 100081, China

Reprint Author's Address:

  • [yang, rong-jie]school of materials, beijing university of technology, beijing; 100081, china

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Source :

Chinese Journal of Explosives and Propellants

ISSN: 1007-7812

Year: 2019

Issue: 5

Volume: 42

Page: 460-464

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 6

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