A　new　type　of　acetylene　black　(AB)　loading　La2O3-Co/AB　catalyst　derived　from　rare　earth　(RE)　La-doped　zeolite　imidazole　framework-67　(ZIF-67)　was　prepared　by　composite　synthesis　strategy　to　make　up　for　the　defects　of　the　weak　activity　and　conductivity　of　single　transition　metal　catalysts.　The　different　coordination　forms　of　La　and　cobalt　hinder　the　growth　of　La-ZIF-67　crystals　and　promote　the　exposure　of　active　sites,　and　the　La2O3　in　the　pyrolysis　product　improves　the　stability　of　the　catalyst.　The　introduction　of　AB　provided　abundant　anchor　sites　to　facilitate　the　heterojunctions　formation　and　the　electronic　transfer　at　the　interface.　Remarkably,　La2O3-Co/AB　showed　high　ORR　half-wave　potential　and　low　OER　overpotential,　which　is　believed　to　benefit　from　the　rich　CoNx　local　environment,　heterostructure　with　internal　electric　field　and　oxygen　vacancies.