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Author:

Xu, Haibo (Xu, Haibo.) | Lu, Qingmei (Lu, Qingmei.) | Cong, Liying (Cong, Liying.) | Tian, Haowen (Tian, Haowen.) | Liu, Weiqiang (Liu, Weiqiang.) | Liu, Youhao (Liu, Youhao.) | Wang, Yunqiao (Wang, Yunqiao.) | Chen, Jingwu (Chen, Jingwu.) | Yi, Xiaofei (Yi, Xiaofei.) | Yue, Ming (Yue, Ming.) (Scholars:岳明)

Indexed by:

EI Scopus SCIE

Abstract:

The structural and magnetic properties were studied for recycling Nd-Fe-B powders from Nd-Fe-B sintered magnets sludge via reduction diffusion (RD) with calcium hydride (CaH2) particles. For comparison, traditional reducing agent calcium granules were applied to prepare recycled Nd-Fe-B powders. Finer particle size and better size distribution as well as lower impurity content are achieved by using CaH2 instead of Ca. In detail, the average particle size of the recycled Nd-Fe-BB powder is reduced from 4.66 to 3.43 mm, and the bimodal distribution disappears. Moreover, the residual calcium content and oxygen content are reduced to about 0.080 wt% and 0.32 wt%. As a consequence, the room-temperature magnetization of the CaH2-recycled Nd-Fe-B powder is increased to 146.30 emu/g, 6.8% and 33%, respectively, higher than that of Ca-reduced powder and the initial sludge. Further analysis indicates that CaH2 is able to reduce the sludge at lower temperature to fabricate well-dispersed, uniform recycled powder with high magnetization arising from a combination factors of its low melting point, low thermodynamic behavior, and the release of hydrogen during the reaction. (c) 2021 Chinese Society of Rare Earths. Published by Elsevier B.V. All rights reserved.

Keyword:

Magnetic properties Reduction diffusion Rare earths Recycled Nd-Fe-B powders Microstructure Reducing agent

Author Community:

  • [ 1 ] [Xu, Haibo]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 2 ] [Lu, Qingmei]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 3 ] [Cong, Liying]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 4 ] [Tian, Haowen]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 5 ] [Liu, Weiqiang]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 6 ] [Yue, Ming]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 7 ] [Lu, Qingmei]State Key Lab Rare Earth Permanent Magnet Mat, Hefei 231500, Peoples R China
  • [ 8 ] [Liu, Weiqiang]State Key Lab Rare Earth Permanent Magnet Mat, Hefei 231500, Peoples R China
  • [ 9 ] [Liu, Youhao]State Key Lab Rare Earth Permanent Magnet Mat, Hefei 231500, Peoples R China
  • [ 10 ] [Chen, Jingwu]State Key Lab Rare Earth Permanent Magnet Mat, Hefei 231500, Peoples R China
  • [ 11 ] [Yi, Xiaofei]State Key Lab Rare Earth Permanent Magnet Mat, Hefei 231500, Peoples R China
  • [ 12 ] [Yue, Ming]State Key Lab Rare Earth Permanent Magnet Mat, Hefei 231500, Peoples R China
  • [ 13 ] [Liu, Youhao]EarthPanda Adv Magnet Mat Co Ltd, Hefei 231500, Peoples R China
  • [ 14 ] [Chen, Jingwu]EarthPanda Adv Magnet Mat Co Ltd, Hefei 231500, Peoples R China
  • [ 15 ] [Yi, Xiaofei]EarthPanda Adv Magnet Mat Co Ltd, Hefei 231500, Peoples R China
  • [ 16 ] [Wang, Yunqiao]Beijing Zhong Ke San Huan Res, Beijing 102200, Peoples R China

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Source :

JOURNAL OF RARE EARTHS

ISSN: 1002-0721

Year: 2022

Issue: 12

Volume: 40

Page: 1905-1912

4 . 9

JCR@2022

4 . 9 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:53

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 11

SCOPUS Cited Count: 12

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 9

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