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Author:

Wang, Changlong (Wang, Changlong.) | Wu, Yufeng (Wu, Yufeng.) | Bodach, Alexander (Bodach, Alexander.) | Krebs, Moritz Lukas (Krebs, Moritz Lukas.) | Schuhmann, Wolfgang (Schuhmann, Wolfgang.) | Schueth, Ferdi (Schueth, Ferdi.)

Indexed by:

EI Scopus SCIE

Abstract:

Hydrogen generated in electrolyzers is discussed as a key element in future energy scenarios, but oxygen evolution as the standard anode reaction is a complex multi-step reaction requiring a high overpotential. At the same time,it does not add value-the oxygen is typically released into the atmosphere. Alternative anode reactions which can proceed at similar current densities as the hydrogen evolution are, therefore, of highest interest. We have discovered a high-performance electrode based on earth-abundant elements synthesized in the presence of H2O2, which is able to sustain current densities of close to 1 A cm(-2) for the oxidation of many organic molecules, which are partly needed at high production volumes. Such anode reactions could generate additional revenue streams, which help to solve one of the most important problems in the transition to renewable energy systems, i.e. the cost of hydrogen electrolysis.

Keyword:

FDCA NiFe Electrode H2O2 High Current Density Anodic Oxidation

Author Community:

  • [ 1 ] [Wang, Changlong]MPI Kohlenforsch, Kaiser Wilhelm Platz 1, D-45470 Mulheim, Germany
  • [ 2 ] [Bodach, Alexander]MPI Kohlenforsch, Kaiser Wilhelm Platz 1, D-45470 Mulheim, Germany
  • [ 3 ] [Krebs, Moritz Lukas]MPI Kohlenforsch, Kaiser Wilhelm Platz 1, D-45470 Mulheim, Germany
  • [ 4 ] [Schueth, Ferdi]MPI Kohlenforsch, Kaiser Wilhelm Platz 1, D-45470 Mulheim, Germany
  • [ 5 ] [Wang, Changlong]Beijing Univ Technol, Inst Circular Econ, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 6 ] [Wu, Yufeng]Beijing Univ Technol, Inst Circular Econ, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 7 ] [Schuhmann, Wolfgang]Ruhr Univ Bochum, Analyt Chem Ctr Electrochem Sci CES, Univ Str 150, D-44780 Bochum, Germany
  • [ 8 ] [Schuhmann, Wolfgang]Ruhr Univ Bochum, Fac Chem & Biochem, Univ Str 150, D-44780 Bochum, Germany

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Source :

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

ISSN: 1433-7851

Year: 2022

Issue: 7

Volume: 62

1 6 . 6

JCR@2022

1 6 . 6 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:53

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 38

SCOPUS Cited Count: 65

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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