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Author:

Yu, Hao-Chih (Yu, Hao-Chih.) | You, Shu-Wen (You, Shu-Wen.) | Wang, Can (Wang, Can.) | Deng, Ji-Guang (Deng, Ji-Guang.) | Hsi, Hsing-Cheng (Hsi, Hsing-Cheng.)

Indexed by:

EI Scopus SCIE

Abstract:

A commercially available beaded activated carbon (KBAC) was selected for combination with a novel electrothermal swing system in examining the Joule heating effects on the physical and chemical properties of activated carbon and its adsorption regenerability at various regeneration temperatures (120, 140, and 160 & DEG;C) after saturation by toluene (TOL) and methylethylketone (MEK). The specific surface area (1278 m(2) g(- 1)) and micropore volume (0.48 cm(3) g(- 1)) for KBAC after one adsorption/desorption cycle were slightly reduced, while KBAC micropore surface area (1158 m(2) g(- 1)) and micropore volume decreased significantly after six adsorption/desorption cycles. It can be inferred that the pores of KBAC, especially micropores, are blocked by heel buildup caused mainly by formation of cracked TOL and MEK coke generated by cyclic Joule heating. The desorption efficiencies of TOL-KBAC and MEK-KBAC (KBAC saturated with TOL and MEK, respectively) evaluated per the gravimetric method ranged from 55 to 80 and 85-90%, respectively, and both showed great correlation between regeneration temperature and desorption efficiency. Notably, the desorption efficiencies calculated from the integral method based on breakthrough curves were 8 and 16% lower than those directly obtained by the gravitational method for TOL-KBAC and MEK-KBAC, respectively. The larger difference in desorption efficiency evaluated by the two methods for MEK-KBAC is likely caused by the decomposition of MEK into CO or CO2, which was less prominent in TOL-KBAC. In the cyclic adsorption/desorption tests, the adsorption capacities of both TOL-KBAC and MEK-KBAC decreased after the 6-cycle electrothermal swing regeneration, such that TOL-KBAC adsorption capacity significantly reduced to around 50%, while that of MEK-KBAC retained around 70% of their respective original adsorption capacities. As aforementioned, heel buildup blocks the pores and leads to decreasing adsorption, especially for TOL.

Keyword:

Volatile organic compounds Electrothermal swing regeneration Methylethylketone Toluene Beaded activated carbon

Author Community:

  • [ 1 ] [Yu, Hao-Chih]Natl Taiwan Univ, Grad Inst Environm Engn, Taipei 10617, Taiwan
  • [ 2 ] [You, Shu-Wen]Natl Taiwan Univ, Grad Inst Environm Engn, Taipei 10617, Taiwan
  • [ 3 ] [Hsi, Hsing-Cheng]Natl Taiwan Univ, Grad Inst Environm Engn, Taipei 10617, Taiwan
  • [ 4 ] [Wang, Can]Tianjin Univ, Sch Environm Sci & Engn, Tianjin 300072, Peoples R China
  • [ 5 ] [Wang, Can]Tianjin Key Lab Indoor Air Environm Qual Control, Tianjin 300072, Peoples R China
  • [ 6 ] [Deng, Ji-Guang]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China

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Source :

SUSTAINABLE ENVIRONMENT RESEARCH

ISSN: 2468-2039

Year: 2022

Issue: 1

Volume: 32

4 . 9

JCR@2022

4 . 9 0 0

JCR@2022

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 4

SCOPUS Cited Count: 4

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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