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Abstract:
The wastewater produced during tertiary oil recovery often contains a large amount of hydrolyzed polyacrylamide (HPAM), which is difficult to treat using conventional biological methods because of its high molecular weight and viscosity. Electrochemical methods are considered to be effective for the treatment of refractory wastewater. In this study, the electrochemical degradation of HPAM using several anode materials was investigated. The results show that the highest HPAM removal efficiency was obtained when iron was used as the anode. The effects of the reaction time, voltage, current density, electrode distance, initial pH, and temperature on the efficiency of HPAM removal were investigated using single-factor experiments, and the HPAM removal rate was found to depend most strongly on the reaction time, voltage, and initial pH. Based on these results, Box-Behnken design was used to optimize the electrochemical treatment of HPAM, and the optimal conditions for HPAM removal were determined to be the following: voltage = 7.6 V, pH = 4.7, and reaction time = 10.5 min. The optimal conditions were tested experimentally, and the HPAM removal efficiency was found to be 98.4%, which fell within the 95% confidence interval of the model results. Analysis of the degradation mechanism showed that HPAM removal occurred mainly via electro-coagulation, with a contribution rate of 83%, together with electro-oxidation, and that the degradation intermediates included ammonia and ethers. Therefore, this electrochemical technique is effective for treatment of wastewater containing HPAM.
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DESALINATION AND WATER TREATMENT
ISSN: 1944-3994
Year: 2020
Volume: 179
Page: 148-159
1 . 1 0 0
JCR@2022
ESI Discipline: ENGINEERING;
ESI HC Threshold:115
Cited Count:
WoS CC Cited Count: 2
SCOPUS Cited Count: 2
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 5
Affiliated Colleges: