As　typical　air　pollutants,　CO,　CH4,　and　volatile　organic　compounds　(VOCs)　have　received　great　attention　due　to　their　negative　impact　on　the　environment　and　human　health.　Heterogeneous　catalysts　are　widely　used　in　the　catalytic　removal　of　exhaust　emission　from　industrial　and　automobile　sources　but　still　suffer　from　deactivation　because　of　various　factors.　The　development　of　a　catalyst　with　excellent　catalytic　stability　is　highly　desired.　We　herein　summarized　the　recent　progress　for　enhancing　the　catalytic　stability　of　catalysts　and　tried　to　obtain　an　in-depth　understanding　of　the　long-term　durability,　resistance　to　sinter,　and　tolerance　for　multi-impurities.　Finally,　the　current　challenges　and　future　perspectives　for　developing　stable　and　highly　efficient　catalysts　in　the　fields　of　synergistic　catalytic　removal　of　pollutants　or　resource　utilization　of　VOCs　via　the　selective　catalytic　oxidation　are　proposed.