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Abstract:
Ceramic-based composites generally have low fracture toughness, and toughening these materials without sacrificing their hardness has been a big challenge. This study presents an approach for toughening ceramic-based composites by modulating the strain partition and stress distribution in phase-boundary regions. A new concept of homogenizing the lattice strain to achieve high fracture toughness in ceramic-based composites is proposed based on the collective lattice shear of martensitic phase transformation. The strategy was demonstrated by ZrO2-containing WC-Co ceramic-metal composites as a prototype. The crystal planes along the WC/ZrO2 martensitic transforming phase boundaries exhibited significantly larger and uniform lattice strains compared with conventional dislocation pile-up phase boundaries with highly localized lattice strains. The homogeneous strain and stress distributions across interfaces enabled the composite to have simultaneously high fracture toughness and hardness. The “homogenizing the lattice strain” strategy proposed in this work is applicable to a broad range of ceramic-based composites to achieve superior comprehensive mechanical properties. © 2023 American Chemical Society.
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ACS Applied Materials and Interfaces
ISSN: 1944-8244
Year: 2023
Issue: 15
Volume: 15
Page: 19604-19615
9 . 5 0 0
JCR@2022
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:26
Cited Count:
WoS CC Cited Count: 0
SCOPUS Cited Count: 11
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 4
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