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Abstract:
Homogeneous ion transport during Li+ plating/stripping plays a significant role in the stability of Li metal anodes (LMAs) and the electrochemical performance of Li metal batteries (LMBs). Controlled ion transport with uniform Li+ distribution is expected to suppress notorious Li dendrite growth while stabilizing the susceptible solid electrolyte interfacial (SEI) film and optimizing the electrochemical stability. Here, we are committed to rendering a comprehensive study of Li+ transport during the Li plating/stripping process related to the interactions between the Li dendrites and SEI film. Moreover, rational ion modulation strategies based on functional separators, artificial SEI films, solid-state electrolytes and structured anodes are introduced to homogenize Li+ flux and stabilize the lithium metal surface. Finally, the current issues and potential opportunities for ion transport regulation to boost the high energy density of LMBs are described.
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Source :
MATERIALS HORIZONS
ISSN: 2051-6347
Year: 2023
Issue: 9
Volume: 10
Page: 3218-3236
1 3 . 3 0 0
JCR@2022
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:26
Cited Count:
WoS CC Cited Count: 6
SCOPUS Cited Count: 6
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 5
Affiliated Colleges: