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Abstract:
n recent years,several nanoparticles have been studied as potential nucleation seeds for cement hydration. Synthetic nano-calcium silicate hydrate (C-S-H),nano-SiO2,nano-CaCO3,nano-TiO2,and carbon nanotubes are investigated to determine their abilities to reduce the nucleation barrier by providing nucleation sites for hydration products,thereby accelerating cement hydration. Among them,the nano C-S-H seeds are found to be a good nucleation substrate for C-S-H gel,and provided the most significant cement-hydration acceleration. Thus,nano C-S-H seeds are attracting increasing attention from both academia and industry. To date,methods of synthesizing nano C-S-H seeds,as well as the seed nucleation process and mechanism of cement hydration,have all been studied. In many studies,the nano C-S-H suspension is prepared by co-precipitating in the presence of polymer that exhibited nanoscale-sized grains and good dispersion stability which followed a non-classical nucleation mode. After applying it to cement,nano C-S-H seeds,with a high surface area,acted as additional nucleation sites for C-S-H gel,which reduced the nucleation barrier of the C-S-H gel. Thus,the nano C-S-H seeds effectively accelerated the cement hydration rate. The nano C-S-H seeds also enhanced the early strength development of the cement, particularly within the first day of aging. In contrast to traditional cement accelerators,nano C-S-H seeds have the advantages of low dosing requirements,good effect on early strength,and no impact on cement and concrete durability. To a certain extent,these seeds also compensate for the slow early-strength growth of supplementary cementitious materials(SCMs). Therefore,nano C-S-H seeds have promising applications in low-temperature and slipform construction,the production of precast-concrete products,and other projects that require high levels of early strength. Nano C-S-H seeds have the potential to become a widely used hydration accelerator for cement and concrete. In this review,many studies about nano C-S-H seeds are analyzed and summarized. Including the methods for synthesizing C-S-H seeds,as well their nucleation process,mechanism of interaction with polymers,and effects on the cement-hydration process. Based on theoretical principles and experimental results,current shortcomings are evaluated,and the problems that still need to be addressed are identified. This review provides a theoretical basis and future direction for scientific research and engineering applications of nano C-S-H seeds. © 2023 Cailiao Daobaoshe/ Materials Review. All rights reserved.
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Materials Reports
ISSN: 1005-023X
Year: 2023
Issue: 9
Volume: 37
Cited Count:
WoS CC Cited Count: 0
SCOPUS Cited Count: 8
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 14
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