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Author:

Ma, Liwen (Ma, Liwen.) | Liu, Guangyun (Liu, Guangyun.) | Wang, Yuehua (Wang, Yuehua.) | Xi, Xiaoli (Xi, Xiaoli.) (Scholars:席晓丽)

Indexed by:

Scopus SCIE

Abstract:

In this study, LiNi0.8Co0.15Al0.05O2@x%Al(2)O(3-)coated cathode materials were regeneratively compounded by the solid-phase sintering method, and their structural characterization and electrochemical performance were systematically analyzed. The regenerated ternary cathode material precursor synthesized by the co-precipitation method was roasted with lithium carbonate at a molar ratio of 1:1.1, and then completely mixed with different contents of aluminum hydroxide. The combined materials were then sintered at 800 & DEG;C for 15 h to obtain the regenerated coated cathode material, LiNi0.8Co0.15Al0.05O2@x%Al2O3. The thermogravimetry analysis, phase composition, morphological characteristics, and other tests show that when the added content of aluminum hydroxide is 3%, the regenerated cathode material, LiNi0.8Co0.15Al0.05O2@1.5%Al2O3, exhibits the highest-order layered structure with Al2O3 coating. This material can better inhibit the production of Ni2+, and improve material structure and electrochemical properties. The first charge-discharge efficiency of the battery assembled with this regenerated cathode material is 97.4%, a 50-cycle capacity retention is 93.4%, and a 100-cycle capacity retention is 87.6%. The first charge-discharge efficiency is far better than that of the uncoated regenerated battery.

Keyword:

coated cathode materials regeneration spent power lithium-ion battery solid phase sintering

Author Community:

  • [ 1 ] [Ma, Liwen]Beijing Univ Technol, Fac Mat & Mfg, Collaborat Innovat Ctr Capital Resource Recycling, Beijing 100124, Peoples R China
  • [ 2 ] [Liu, Guangyun]Beijing Univ Technol, Fac Mat & Mfg, Collaborat Innovat Ctr Capital Resource Recycling, Beijing 100124, Peoples R China
  • [ 3 ] [Xi, Xiaoli]Beijing Univ Technol, Fac Mat & Mfg, Collaborat Innovat Ctr Capital Resource Recycling, Beijing 100124, Peoples R China
  • [ 4 ] [Ma, Liwen]Beijing Univ Technol, Natl Engn Lab Ind Big Data Applicat Technol, Beijing 100124, Peoples R China
  • [ 5 ] [Wang, Yuehua]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 6 ] [Xi, Xiaoli]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China

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Source :

MOLECULES

Year: 2023

Issue: 13

Volume: 28

4 . 6 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:20

Cited Count:

WoS CC Cited Count: 2

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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