A　TiO2/ZnO　composite　film　which　served　as　the　bind-free　anode　for　lithium-ion　battery　was　rapidly　constructed　on　Ti　foil　by　the　one-step　plasma　electrolytic　oxidation　process.　The　fabricated　TiO2-based　transition　metal　oxide　composites　took　advantage　of　the　high　theoretical　capacity　of　ZnO　and　the　good　structural　stability　of　TiO2,　showing　a　high　specific　capacity　(706.2　mAh　g(-1)　over　400　cycles　at　0.1　A　g(-1))　and　a　good　rate　capability　(capacity　reversible　after　2.0　A　g(-1)).　When　the　scan　rate　gradually　elevated　from　0.2　to　1.0　mV　s(-1),　the　pseudocapacitance　contribution　increased　from　63.9%　to　81.2%.　Besides,　the　hole-containing　morphology　of　the　film　guaranteed　efficient　diffusion　and　excellent　dynamic　characteristics　for　Li　(+　).　The　whole　film　preparation　process　was　accompanied　by　a　facile　in-liquid　plasma　discharge　with　an　average　electron　temperature　of　3519　K.　This　high-efficiency　and　low-cost　approach　extends　the　practical　territory　of　transition　metal　oxide　anodes.