The　water　sorption　and　desorption　properties　of　solid　adsorbent　materials　are　crucial　in　rotary　dehumidification　systems.　Metal　organic　frameworks　(MOFs)　and　hydrogels　are　mostly　at　the　laboratory　stage　due　to　factors　like　the　synthesis　process　and　yield.　In　this　study,　we　utilized　an　eco-friendly　and　large-scale　synthesis　method　to　prepare　polyacrylamide　(PAM)　hydrogels　(yielding　approximately　500　mL　from　a　single　polymerization).　Subsequently,　PAM　was　then　coated　onto　glass　fiber　paper　(GFP),　which　serves　as　a　commonly　employed　substrate　in　desiccant　wheels.　By　incorporating　the　hygroscopic　salt　LiCl　and　optimizing　the　content　of　each　component,　the　water　sorption　performance　of　the　composite　was　notably　improved.　The　water　sorption　and　desorption　performances,　as　well　as　cycling　stability,　were　evaluated　and　compared　with　composites　containing　aluminum　fumarate,　LiCl,　and　GFP　(AlFum-LiCl&GFP).　The　results　revealed　that　PAM-LiCl&GFP　outperformed　AlFum-LiCl&GFP　in　terms　of　sorption　capacity　throughout　various　relative　humidity　(RH)　levels.　It　achieved　a　water　uptake　of　1.06　g　center　dot　g-1　at　25　degrees　C　and　30%　RH,　corresponding　to　a　water　sorption　rate　coefficient　K　of　15.32　x　10-4　s-1.　Furthermore,　the　lower　desorption　temperature　(60　degrees　C)　resulting　in　a　desorption　ratio　of　82.6%,　along　with　the　excellent　cycling　stability　and　effective　performance　as　a　desiccant　wheel　module,　provide　evidence　for　the　potential　application　of　PAM-LiCl&GFP　in　desiccant　wheels.