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Author:

Gao, Qi (Gao, Qi.) | Ye, Qing (Ye, Qing.) (Scholars:叶青) | Han, Shuai (Han, Shuai.) | Cheng, Shuiyuan (Cheng, Shuiyuan.) (Scholars:程水源) | Kang, Tianfang (Kang, Tianfang.) (Scholars:康天放) | Dai, Hongxing (Dai, Hongxing.) (Scholars:戴洪兴)

Indexed by:

Scopus SCIE

Abstract:

The Ce-Cu-SAPO-18 samples were prepared by the ion exchange method. Physicochemical properties of the samples were systematically characterized by a number of analytical techniques, and Ce doping and hydrothermal temperature effects on NH3-SCR activity of Cu-SAPO-18 were also investigated. The results show that doping of Ce increased NH3-SCR activity and hydrothermal stability of the Cu-SAPO-18 sample. After Ce doping, a more amount of the isolated Cu2+ ions entered the D6R and the catalyst structure was more stable. The structure and catalytic activity of Ce-Cu-SAPO-18 remained almost intact after hydrothermal aging at 650 degrees C. After hydrothermal aging at 850 degrees C, however, the structure of Ce-Cu-SAPO-18 was greatly destroyed, and its catalytic activity declined remarkably. The high-temperature hydrothermal aging treatment led to decreases in amount of the isolated Cu2+ ions and acidic sites, destroying in the zeolitic structure, and drop in NH3-SCR activity.

Keyword:

Selective catalytic reduction Cu-SAPO-18 NH3-SCR Ce-Cu-SAPO-18 Hydrothermal aging treatment

Author Community:

  • [ 1 ] [Gao, Qi]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Dept Environm Sci, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Ye, Qing]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Dept Environm Sci, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Han, Shuai]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Dept Environm Sci, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Cheng, Shuiyuan]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Dept Environm Sci, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Kang, Tianfang]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Dept Environm Sci, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 6 ] [Dai, Hongxing]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control, Key Lab Adv Funct Mat,Educ Minist China, Beijing 100124, Peoples R China
  • [ 7 ] [Dai, Hongxing]Beijing Univ Technol, Lab Catalysis Chem & Nanosci, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Beijing 100124, Peoples R China

Reprint Author's Address:

  • 叶青 戴洪兴

    [Ye, Qing]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Dept Environm Sci, Coll Environm & Energy Engn, Beijing 100124, Peoples R China;;[Dai, Hongxing]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control, Key Lab Adv Funct Mat,Educ Minist China, Beijing 100124, Peoples R China;;[Dai, Hongxing]Beijing Univ Technol, Lab Catalysis Chem & Nanosci, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Beijing 100124, Peoples R China

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Source :

CATALYSIS SURVEYS FROM ASIA

ISSN: 1571-1013

Year: 2020

Issue: 2

Volume: 24

Page: 134-142

3 . 0 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:139

Cited Count:

WoS CC Cited Count: 6

SCOPUS Cited Count: 9

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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