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Author:

Zhang, Tie-Jun (Zhang, Tie-Jun.) | Li, Jian (Li, Jian.) (Scholars:李坚) | He, Hong (He, Hong.) (Scholars:何洪) | Liang, Wen-Jun (Liang, Wen-Jun.) (Scholars:梁文俊) | Liang, Quan-Ming (Liang, Quan-Ming.)

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EI Scopus PKU CSCD

Abstract:

Sb-V2O5-TiO2 catalysts were prepared by wet impregnation method. The effect of antimony loadings and calcination temperatures on the activity of catalysts were investigated on the basis of 3%V2O5-TiO2. The results indicate that the catalyst with 11% Sb loading, calcined at 500, has the best activity of SCR. The NOx conversion could reach 92% at 170 with the inlet NOx concentration of 0.07%, the O2 volume fraction of 5%, and the space velocity of 27 000 h-1. The H2-TPR data reveal that the increase of activity can be attributed to the promotion of the catalyst oxidation ability by the modifying of antimony. Sb is mainly in the pentavalent antimony form on the surface of the catalyst, and the increase in surface acidity of the catalyst is identified by means of XPS and NH3-TPD. The effects of SO2 and H2O on the catalyst is also studied, showing that the Sb-V2O5-TiO2 has an excellent catalytic activity in the presence of H2O and SO2. FT-IR, TG and pore structure test results suggest that the addition of Sb can effectively inhibit the aggregation of ammonium sulfate on the catalyst surface, thereby improving the service life of the catalyst. © 2017, Science Press. All right reserved.

Keyword:

Thyristors Titanium Vanadium Calcination Pore structure Sulfur compounds Temperature Nitrogen oxides Ammonia Oxide minerals Catalyst activity Titanium dioxide Vanadium pentoxide Antimony

Author Community:

  • [ 1 ] [Zhang, Tie-Jun]Key Laboratory of Beijing on Regional Air Pollution Control, Beijing University of Technology, Beijing; 100124, China
  • [ 2 ] [Li, Jian]Key Laboratory of Beijing on Regional Air Pollution Control, Beijing University of Technology, Beijing; 100124, China
  • [ 3 ] [He, Hong]Key Laboratory of Beijing on Regional Air Pollution Control, Beijing University of Technology, Beijing; 100124, China
  • [ 4 ] [Liang, Wen-Jun]Key Laboratory of Beijing on Regional Air Pollution Control, Beijing University of Technology, Beijing; 100124, China
  • [ 5 ] [Liang, Quan-Ming]Key Laboratory of Beijing on Regional Air Pollution Control, Beijing University of Technology, Beijing; 100124, China

Reprint Author's Address:

  • 李坚

    [li, jian]key laboratory of beijing on regional air pollution control, beijing university of technology, beijing; 100124, china

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Source :

Journal of Fuel Chemistry and Technology

ISSN: 0253-2409

Year: 2017

Issue: 6

Volume: 45

Page: 740-746

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 11

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