A　series　of　aggregation-induced　emission　(AIE)　active　polysiloxanes　(P7-1~P7-2,　P29-1~P29-6)　were　prepared　through　hydrosilylation　between　polymethylhydrosiloxane　(PMHS,　DP=7　or　29)　and　AIE-active　vinyl　monomer　1-(4＇-allyloxy-biphenyl)-2,5-diphenyl　pyrrole　(M-TPP),　or　with　optical　active　monomer　cholesteryl　allyloxy　ether　(M-Chol*).　Monomer　M-TPP　and　all　of　the　polymers　exhibits　aggeragation-induced　emission　enhancement　properties.　The　fluorescence　intensity　of　M-TPP　in　THF/H2O　mixtures　increases　when　the　water　fraction　is　higher　than　60%,　while　is　over　20%　for　polysiloxanes,　which　mainly　because　the　entanglement　of　the　flexible　polysiloxane　main-chain　can　restrict　the　molecular　motion　of　triphenylpyrrole　(TPP)　derivates　and　induce　the　increasing　of　the　fluorescence　intensity.　Moreover,　the　maximum　relative　fluorescence　intensity　(I/I0)　is　equal　to　4　for　M-TPP　and　1.4~4.9　for　polysiloxanes,　and　the　grafted　degree　of　the　TPP　derivative　has　effect　on　the　AIE　properties　of　polymers.　The　specific　optical　rotations　of　the　chiral　polymers　increase　with　increasing　the　content　of　chiral　cholesteryl　ether　moieties.　All　the　target　polymers　possess　good　thermal　stabilities　and　their　decomposition　points　(Td)　are　greater　than　320°C.