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Author:

Li, Wen (Li, Wen.) | Li, Yunyun (Li, Yunyun.) | Wang, Ying (Wang, Ying.) | Zhou, Zhengyang (Zhou, Zhengyang.) | Wang, Chao (Wang, Chao.) | Sun, Yiyang (Sun, Yiyang.) | Sheng, Jianyong (Sheng, Jianyong.) | Xiao, Jiawen (Xiao, Jiawen.) (Scholars:肖家文) | Wang, Qian (Wang, Qian.) | Kurosawa, Shunsuke (Kurosawa, Shunsuke.) | Buryi, Maksym (Buryi, Maksym.) | John, David (John, David.) | Paurova, Karin (Paurova, Karin.) | Nikl, Martin (Nikl, Martin.) | Ouyang, Xiaoping (Ouyang, Xiaoping.) | Wu, Yuntao (Wu, Yuntao.)

Indexed by:

EI Scopus SCIE

Abstract:

The urgency for cost-effective, high-resolution, flexible X-ray imaging detectors is generating great demand for scintillators with low-temperature processability, high scintillation yield, and negligible afterglow. X-ray imaging materials are currently dominated by inorganic scintillators in the form of rigid films and bulk crystals, which have inherent limitations including high-temperature, complex synthesis, and considerable challenges toward advanced nonplanar imaging. Here, high-performance and flexible X-ray scintillators based on novel zero-dimensional (0D) (BTPP)2MnX4 (BTPP = benzyltriphenylphosphonium; X = Cl, Br) halides are reported. They emit bright green light originating from the 4T1-6A1 transition of Mn2+ under X-ray excitation. In particular, (BTPP)2MnBr4 single crystals exhibit excellent air- and radiation-stability, a high scintillation yield of 53 000 photons MeV-1, a low detection limit of 89.9 nGyair s-1, and an ultralow afterglow comparable to commercial Bi4Ge3O12 (BGO) single crystals. Moreover, the (BTPP)2MnCl4@polydimethylsiloxane (PDMS) flexible scintillation screens achieve a high spatial resolution of 14.1 lp mm-1 and realize high-quality imaging results of nonplanar objects. This study demonstrates that the flexible scintillation screens based on low-dimensional Mn(II) hybrid halides have significant potential for low-dose and high-resolution X-ray imaging applications. The green-emitting (BTPP)2MnX4 (X = Cl, Br) flexible scintillation screens demonstrate high scintillation yield, decent X-ray detection limit, ultralow afterglow, high radiation resistance, superior imaging spatial resolution, and high-quality imaging results for both planar and nonplanar imaging objects. These results highlight the great potential of developing low-dimensional Mn(II) hybrid halides for X-ray detection and imaging applications.image

Keyword:

hybrid scintillators manganese halides scintillation screens X-ray imaging

Author Community:

  • [ 1 ] [Li, Wen]Chinese Acad Sci, Shanghai Inst Ceram, Artificial Crystal Res Ctr, Shanghai 201899, Peoples R China
  • [ 2 ] [Li, Yunyun]Chinese Acad Sci, Shanghai Inst Ceram, Artificial Crystal Res Ctr, Shanghai 201899, Peoples R China
  • [ 3 ] [Wang, Qian]Chinese Acad Sci, Shanghai Inst Ceram, Artificial Crystal Res Ctr, Shanghai 201899, Peoples R China
  • [ 4 ] [Wu, Yuntao]Chinese Acad Sci, Shanghai Inst Ceram, Artificial Crystal Res Ctr, Shanghai 201899, Peoples R China
  • [ 5 ] [Wang, Ying]Beijing Univ Technol, Fac Mat & Mfg, Beijing Key Lab Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 6 ] [Wang, Chao]Beijing Univ Technol, Fac Mat & Mfg, Beijing Key Lab Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 7 ] [Xiao, Jiawen]Beijing Univ Technol, Fac Mat & Mfg, Beijing Key Lab Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 8 ] [Zhou, Zhengyang]Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine M, Shanghai 201899, Peoples R China
  • [ 9 ] [Sun, Yiyang]Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine M, Shanghai 201899, Peoples R China
  • [ 10 ] [Sheng, Jianyong]Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine M, Shanghai 201899, Peoples R China
  • [ 11 ] [Kurosawa, Shunsuke]Tohoku Univ, NICHe, 6-6-10 Aza Aoba,Aoba Ku, Sendai, Miyagi 9808579, Japan
  • [ 12 ] [Kurosawa, Shunsuke]Tohoku Univ, Inst Mat Res, 2-1-1 Katahira,Aoba Ku, Sendai, Miyagi 9808577, Japan
  • [ 13 ] [Kurosawa, Shunsuke]Osaka Univ, Inst Laser Engn, 2-6 Yamadaoka, Suita, Osaka 5650871, Japan
  • [ 14 ] [Buryi, Maksym]Czech Acad Sci, FZU Inst Phys, Slovance 1999-2, Prague 18200, Czech Republic
  • [ 15 ] [John, David]Czech Acad Sci, FZU Inst Phys, Slovance 1999-2, Prague 18200, Czech Republic
  • [ 16 ] [Paurova, Karin]Czech Acad Sci, FZU Inst Phys, Slovance 1999-2, Prague 18200, Czech Republic
  • [ 17 ] [Nikl, Martin]Czech Acad Sci, FZU Inst Phys, Slovance 1999-2, Prague 18200, Czech Republic
  • [ 18 ] [Buryi, Maksym]Fac Nucl Sci & Phys Engn, Brehova 7, Prague, Czech Republic
  • [ 19 ] [John, David]Fac Nucl Sci & Phys Engn, Brehova 7, Prague, Czech Republic
  • [ 20 ] [Nikl, Martin]Fac Nucl Sci & Phys Engn, Brehova 7, Prague, Czech Republic
  • [ 21 ] [Paurova, Karin]Univ Chem & Technol, Dept Inorgan Chem, Prague 16628, Czech Republic
  • [ 22 ] [Ouyang, Xiaoping]Northwest Inst Nucl Technol, Xian 710024, Peoples R China

Reprint Author's Address:

  • [Wu, Yuntao]Chinese Acad Sci, Shanghai Inst Ceram, Artificial Crystal Res Ctr, Shanghai 201899, Peoples R China;;[Xiao, Jiawen]Beijing Univ Technol, Fac Mat & Mfg, Beijing Key Lab Microstruct & Property Adv Mat, Beijing 100124, Peoples R China;;[Ouyang, Xiaoping]Northwest Inst Nucl Technol, Xian 710024, Peoples R China;;

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Source :

LASER & PHOTONICS REVIEWS

ISSN: 1863-8880

Year: 2023

Issue: 2

Volume: 18

1 1 . 0 0 0

JCR@2022

Cited Count:

WoS CC Cited Count: 22

SCOPUS Cited Count: 28

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 6

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