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Abstract:
Rare earth ions doped materials, organic dyes and quantum dots are employed to realize the fluorescence temperature sensing which has great significance in aerospace, biomedicine, food storage, etc. Fluorescent materials of inorganic halide perovskite QDs(PeQDs) possess great application prospects in the field of fluorescence temperature sensing due to high quantum yield and strong temperature dependence. However, PeQDs have only one photoluminescence(PL) peak whose intensity and position are highly susceptible to interference from factors such as concentration and size, resulting in low accuracy in temperature sensing using this PL peak alone. In this work, we propose a novel temperature sensing structure using microsphere-cavity-array(MCA)capped PeQDs film(MCA/PeQDs). Fluorescence temperature sensing is realized using the temperature dependent PL peak intensity ratio between the MCA/PeQDs structure and the bare one. Through the Purcell effect induced by microsphere cavity supported whispering-gallery modes(WGMs) in the microsphere cavity, the spontaneous emission rate is enhanced, and the phonon assisted thermal quenching effect is suppressed, which results in better fluorescence enhancement of PeQDs. As a result, when the concentration of PeQDs is 0.131 6 mg/mL and the diameter of the microsphere is (19±1) μm, the absolute sensitivity(Sa) and relative sensitivity(Sr) can achieve 0.75 K-1 and 1.95%·K-1. The present work overcomes the poor accuracy of temperature sensing in single PL peak and opens up a new way for fluorescence materials used in fluorescence temperature sensing with high performance. © 2023 Chines Academy of Sciences. All rights reserved.
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Chinese Journal of Luminescence
ISSN: 1000-7032
Year: 2023
Issue: 10
Volume: 44
Page: 1786-1796
Cited Count:
WoS CC Cited Count: 0
SCOPUS Cited Count: 1
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 7
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