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Author:

Luo, Xiyu (Luo, Xiyu.) | Xu, Weidong (Xu, Weidong.) | Zheng, Guanhaojie (Zheng, Guanhaojie.) | Tammireddy, Sandhya (Tammireddy, Sandhya.) | Wei, Qi (Wei, Qi.) | Karlsson, Max (Karlsson, Max.) | Zhang, Zhaojun (Zhang, Zhaojun.) | Ji, Kangyu (Ji, Kangyu.) | Kahmann, Simon (Kahmann, Simon.) | Yin, Chunyang (Yin, Chunyang.) | Zou, Yatao (Zou, Yatao.) | Zhang, Zeyu (Zhang, Zeyu.) | Chen, Huaiyu (Chen, Huaiyu.) | Marçal, Lucas A.B. (Marçal, Lucas A.B..) | Zhao, Haifeng (Zhao, Haifeng.) | Ma, Dongxin (Ma, Dongxin.) | Zhang, Dongdong (Zhang, Dongdong.) | Lu, Yue (Lu, Yue.) | Li, Mingjie (Li, Mingjie.) | Deibel, Carsten (Deibel, Carsten.) | Stranks, Samuel D. (Stranks, Samuel D..) | Duan, Lian (Duan, Lian.) | Wallentin, Jesper (Wallentin, Jesper.) | Huang, Wei (Huang, Wei.) | Gao, Feng (Gao, Feng.)

Indexed by:

EI Scopus SCIE

Abstract:

Compositional heterogeneity is commonly observed in mixed bromide/iodide perovskite photoabsorbers, typically with minimal effects on charge carrier recombination and photovoltaic performance. Consistently, it has so far received very limited attention in bromide/chloride-mixed perovskites, which hold particular significance for blue light-emitting diodes. Here, we uncover that even a minor degree of localized halide heterogeneity leads to severe non-radiative losses in mixed bromide/chloride blue perovskite emitters, presenting a stark contrast to general observations in photovoltaics. We not only provide a visualization of the heterogeneity landscape spanning from micro-to sub-microscale but also identify that this issue mainly arises from the initially formed chloride-rich clusters during perovskite nucleation. Our work sheds light on a long-term neglected factor impeding the advancement of blue light-emitting diodes using mixed halide perovskites and provides a practical strategy to mitigate this issue. © 2023 The Authors

Keyword:

Perovskite Electroluminescence Photovoltaic effects Chlorine compounds Light emitting diodes

Author Community:

  • [ 1 ] [Luo, Xiyu]Key Lab of Organic Optoelectronics and Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing; 100084, China
  • [ 2 ] [Luo, Xiyu]Department of Physics, Chemistry and Biology (IFM), Linköping University, Linköping, Sweden
  • [ 3 ] [Xu, Weidong]Department of Physics, Chemistry and Biology (IFM), Linköping University, Linköping, Sweden
  • [ 4 ] [Xu, Weidong]Frontiers Science Center for Flexible Electronics, Xi'an Institute of Flexible Electronics (IFE), Northwestern Polytechnical University, 127 West Youyi Road, Xi'an; 710072, China
  • [ 5 ] [Zheng, Guanhaojie]Shanghai Synchrotron Radiation Facility (SSRF), Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai; 201210, China
  • [ 6 ] [Tammireddy, Sandhya]Institut für Physik, Technische Universität Chemnitz, Chemnitz; 09126, Germany
  • [ 7 ] [Wei, Qi]Department of Applied Physics, The Hong Kong Polytechnic University, Kowloon, Hung Hom, Hong Kong
  • [ 8 ] [Karlsson, Max]Department of Physics, Chemistry and Biology (IFM), Linköping University, Linköping, Sweden
  • [ 9 ] [Zhang, Zhaojun]Synchrotron Radiation Research and NanoLund, Department of Physics, Lund University, Lund; 22100, Sweden
  • [ 10 ] [Ji, Kangyu]Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge; CB3 0HE, United Kingdom
  • [ 11 ] [Ji, Kangyu]Department of Chemical Engineering and Biotechnology, University of Cambridge, Philippa Fawcett Drive, Cambridge; CB3 0AS, United Kingdom
  • [ 12 ] [Kahmann, Simon]Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge; CB3 0HE, United Kingdom
  • [ 13 ] [Kahmann, Simon]Department of Chemical Engineering and Biotechnology, University of Cambridge, Philippa Fawcett Drive, Cambridge; CB3 0AS, United Kingdom
  • [ 14 ] [Yin, Chunyang]Department of Physics, Chemistry and Biology (IFM), Linköping University, Linköping, Sweden
  • [ 15 ] [Zou, Yatao]Department of Physics, Chemistry and Biology (IFM), Linköping University, Linköping, Sweden
  • [ 16 ] [Zhang, Zeyu]Institute of Microstructure and Property of Advanced Materials, Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing; 100124, China
  • [ 17 ] [Chen, Huaiyu]Synchrotron Radiation Research and NanoLund, Department of Physics, Lund University, Lund; 22100, Sweden
  • [ 18 ] [Marçal, Lucas A.B.]Synchrotron Radiation Research and NanoLund, Department of Physics, Lund University, Lund; 22100, Sweden
  • [ 19 ] [Marçal, Lucas A.B.]MAX IV Laboratory, Lund University, Lund; 22100, Sweden
  • [ 20 ] [Zhao, Haifeng]Department of Physics, Chemistry and Biology (IFM), Linköping University, Linköping, Sweden
  • [ 21 ] [Ma, Dongxin]Key Lab of Organic Optoelectronics and Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing; 100084, China
  • [ 22 ] [Zhang, Dongdong]Key Lab of Organic Optoelectronics and Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing; 100084, China
  • [ 23 ] [Lu, Yue]Institute of Microstructure and Property of Advanced Materials, Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing; 100124, China
  • [ 24 ] [Li, Mingjie]Department of Applied Physics, The Hong Kong Polytechnic University, Kowloon, Hung Hom, Hong Kong
  • [ 25 ] [Deibel, Carsten]Institut für Physik, Technische Universität Chemnitz, Chemnitz; 09126, Germany
  • [ 26 ] [Stranks, Samuel D.]Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge; CB3 0HE, United Kingdom
  • [ 27 ] [Stranks, Samuel D.]Department of Chemical Engineering and Biotechnology, University of Cambridge, Philippa Fawcett Drive, Cambridge; CB3 0AS, United Kingdom
  • [ 28 ] [Duan, Lian]Key Lab of Organic Optoelectronics and Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing; 100084, China
  • [ 29 ] [Wallentin, Jesper]Synchrotron Radiation Research and NanoLund, Department of Physics, Lund University, Lund; 22100, Sweden
  • [ 30 ] [Huang, Wei]Frontiers Science Center for Flexible Electronics, Xi'an Institute of Flexible Electronics (IFE), Northwestern Polytechnical University, 127 West Youyi Road, Xi'an; 710072, China
  • [ 31 ] [Gao, Feng]Department of Physics, Chemistry and Biology (IFM), Linköping University, Linköping, Sweden

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Matter

ISSN: 2590-2393

Year: 2024

Issue: 3

Volume: 7

Page: 1054-1070

1 8 . 9 0 0

JCR@2022

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 30

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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