• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
搜索

Author:

Pang, W. (Pang, W..) | Li, B. (Li, B..) | Wu, Y. (Wu, Y..) | Zeng, Q. (Zeng, Q..) | Yang, J. (Yang, J..) | Zhang, Y. (Zhang, Y..) | Tian, S. (Tian, S..)

Indexed by:

EI Scopus SCIE

Abstract:

Biodegradable plastics such as Poly (butylene adipate-co-terephthalate) (PBAT) have been extensively utilized in numerous fields. However, post-consumption, PBAT tends to pollute the environment and waste resources. Herein, a novel approach employing a 1,4-butanediol-alkali combined method for the hydrolysis of PBAT is introduced. At 130 °C, with a reaction time of 60 min, the hydrolysis rate of PBAT exceeds 99 %. Subsequently, a two-step synthesis rapidly produces a foam nickel-supported NiOOH catalyst for the electrocatalytic reformation of the PBAT hydrolysate into higher-value chemicals (succinate salts) at an impressive current density of 100 mA cm−2 at 1.43 V (vs. RHE) and a Faradaic efficiency of 97.6 %. Experimental results and density functional theory calculations have elucidated the active state changes of the foam nickel-supported NiOOH catalyst and the intermediates in the oxidation of 1,4-butanediol to succinate, alongside the reaction mechanism. This study offers a viable approach for the degradation of PBAT plastic through a 1,4-butanediol-alkali method and the rapid preparation of a foam nickel-supported NiOOH electrocatalyst, achieving the upgraded recycling of post-consumer biodegradable PBAT plastic. © 2024 Elsevier B.V.

Keyword:

1,4-Butanediol-alkali combined method Upgraded recycling Density Functional Theory NiOOH PBAT

Author Community:

  • [ 1 ] [Pang W.]Institute of Circular Economy, College of Materials Science & Engineering, Beijing University of Technology, Beijing, 100022, China
  • [ 2 ] [Pang W.]State Key Laboratory of Mesoscience and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, 100190, China
  • [ 3 ] [Li B.]Institute of Circular Economy, College of Materials Science & Engineering, Beijing University of Technology, Beijing, 100022, China
  • [ 4 ] [Wu Y.]Institute of Circular Economy, College of Materials Science & Engineering, Beijing University of Technology, Beijing, 100022, China
  • [ 5 ] [Zeng Q.]State Key Laboratory of Mesoscience and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, 100190, China
  • [ 6 ] [Yang J.]State Key Laboratory of Mesoscience and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, 100190, China
  • [ 7 ] [Zhang Y.]State Key Laboratory of Mesoscience and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, 100190, China
  • [ 8 ] [Tian S.]State Key Laboratory of Mesoscience and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, 100190, China

Reprint Author's Address:

Email:

Show more details

Related Keywords:

Source :

Chemical Engineering Journal

ISSN: 1385-8947

Year: 2024

Volume: 486

1 5 . 1 0 0

JCR@2022

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 17

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 6

Affiliated Colleges:

Online/Total:459/10796959
Address:BJUT Library(100 Pingleyuan,Chaoyang District,Beijing 100124, China Post Code:100124) Contact Us:010-67392185
Copyright:BJUT Library Technical Support:Beijing Aegean Software Co., Ltd.