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Author:

Ren, D. (Ren, D..) | Jiang, D. (Jiang, D..) | Huang, Y. (Huang, Y..) | Jin, Y. (Jin, Y..) | Zeng, C. (Zeng, C..) | Zhou, K. (Zhou, K..) | Wang, H. (Wang, H..)

Indexed by:

EI Scopus SCIE

Abstract:

Designing low-content and high-activity Pt-based catalysts with the high durability for the electrochemical hydrogen production remains a challenge. In this study, a ternary metal phosphide (NiCoP) with 1D nanowire (NW) and 2D nanosheet (NS) morphologies incorporating Pt clusters (denoted as Ptcluster-NiCoP@NF NWs and Ptcluster-NiCoP@NF NSs, respectively) was prepared using a hydrothermal–phosphorization–electrodeposition method. Based on the “tip effect” of NWs and a high electrochemical surface area, the as-prepared Ptcluster-NiCoP@NF NWs display better hydrogen evolution reaction (HER) performance, with a low overpotential of 65 mV at a high current density of 100 mA cm−2 and a low Tafel slope of 38.86 mV dec−1, than the Ptcluster-NiCoP@NF NSs, with an overportential of 95 mV at 42.53 mV dec−1. This indicates that the NiCoP NW-based support exhibits faster HER kinetics. The mass activity (11.47 A mgPt−1) of the Ptcluster-NiCoP@NF NWs is higher than that of commercial Pt/C catalysts. Significantly, the Ptcluster-NiCoP@NF NWs display excellent cyclic stability with negligible losses for 5000 cycles and 30-h tests at a high current of 500 mA cm−2. © 2024 Elsevier Inc.

Keyword:

Metal-support interaction Ternary metal phosphide Tip effect Pt nanoclusters Hydrogen evolution reaction

Author Community:

  • [ 1 ] [Ren D.]Key Laboratory for New Functional Materials of Ministry of Education, Institution of Advanced Energy Materials and Devices, Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China
  • [ 2 ] [Jiang D.]Key Laboratory for New Functional Materials of Ministry of Education, Institution of Advanced Energy Materials and Devices, Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China
  • [ 3 ] [Huang Y.]Key Laboratory for New Functional Materials of Ministry of Education, Institution of Advanced Energy Materials and Devices, Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China
  • [ 4 ] [Jin Y.]Key Laboratory for New Functional Materials of Ministry of Education, Institution of Advanced Energy Materials and Devices, Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China
  • [ 5 ] [Zeng C.]Key Laboratory for New Functional Materials of Ministry of Education, Institution of Advanced Energy Materials and Devices, Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China
  • [ 6 ] [Zhou K.]Key Laboratory for New Functional Materials of Ministry of Education, Institution of Advanced Energy Materials and Devices, Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China
  • [ 7 ] [Wang H.]Key Laboratory for New Functional Materials of Ministry of Education, Institution of Advanced Energy Materials and Devices, Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China

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Source :

Journal of Colloid and Interface Science

ISSN: 0021-9797

Year: 2024

Volume: 665

Page: 510-517

9 . 9 0 0

JCR@2022

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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