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Author:

Li, Yongmei (Li, Yongmei.) | Sun, Liangbo (Sun, Liangbo.) | Huang, Shengyang (Huang, Shengyang.) | Xu, Kun (Xu, Kun.) | Zeng, Cheng-Chu (Zeng, Cheng-Chu.) (Scholars:曾程初)

Indexed by:

EI Scopus SCIE

Abstract:

The electro-generation of acyl radicals from both aromatic and aliphatic aldehydes remains an unmet challenge. We provide a solution to this challenge by merging electro-oxidation and a quinuclidine-mediated hydrogen atom transfer strategy. The generation of acyl radicals at decreased applied potentials compared to that of formyl oxidation exhibits excellent functional group compatibility. The electro-generation of acyl radicals from both aromatic and aliphatic aldehydes is a synthetic challenge. We addressed this challenge by merging electro-oxidation and a quinuclidine-mediated HAT strategy.

Keyword:

Author Community:

  • [ 1 ] [Li, Yongmei]Beijing Univ Technol, Coll Chem & Life Sci, Beijing 100124, Peoples R China
  • [ 2 ] [Sun, Liangbo]Beijing Univ Technol, Coll Chem & Life Sci, Beijing 100124, Peoples R China
  • [ 3 ] [Huang, Shengyang]Beijing Univ Technol, Coll Chem & Life Sci, Beijing 100124, Peoples R China
  • [ 4 ] [Xu, Kun]Beijing Univ Technol, Coll Chem & Life Sci, Beijing 100124, Peoples R China
  • [ 5 ] [Zeng, Cheng-Chu]Beijing Univ Technol, Coll Chem & Life Sci, Beijing 100124, Peoples R China

Reprint Author's Address:

  • [Xu, Kun]Beijing Univ Technol, Coll Chem & Life Sci, Beijing 100124, Peoples R China;;[Zeng, Cheng-Chu]Beijing Univ Technol, Coll Chem & Life Sci, Beijing 100124, Peoples R China;;

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Source :

CHEMICAL COMMUNICATIONS

ISSN: 1359-7345

Year: 2024

Issue: 48

Volume: 60

Page: 6174-6177

4 . 9 0 0

JCR@2022

Cited Count:

WoS CC Cited Count: 4

SCOPUS Cited Count: 4

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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