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Author:

Zhu, Guanhua (Zhu, Guanhua.) | Zhu, Ganghui (Zhu, Ganghui.) | Tong, Baocai (Tong, Baocai.) | Zhang, Dasheng (Zhang, Dasheng.) | Wu, Jin (Wu, Jin.) | Zhai, Yuanzheng (Zhai, Yuanzheng.) | Chen, Haiyang (Chen, Haiyang.)

Indexed by:

EI Scopus SCIE

Abstract:

The source diversity and health risk of trace elements (TEs) in soil make it necessary to reveal the relationship between pollution, source, and risk. However, neglect of spatial heterogeneity restricts the reliability of existing identification methods. In this study, spatial heterogeneity is proposed as a necessary and feasible factor for accurately dissecting the pollution-source-risk link of soil TEs. A comprehensive framework is developed by integrating positive matrix factorization, Geodetector, and risk evaluation tools, and successfully applied in a mining-intensive city in northern China. Overall, the TEs are derived from natural background (28.5 %), atmospheric deposition (25.6 %), coal mining (21.8 %), and metal industry (24.1 %). The formation mechanism of heterogeneity for high-variance TEs (Se, Hg, Cd) is first systematically deciphered by revealing the heterogeneous source-sink relationship. Specifically, Se is dominated (76.5 %) by heterogeneous coal mining (q=0.187), Hg is determined (92.6 %) by the heterogeneity of metal mining (q=0.183) and smelting (q=0.363), and Cd is caused (50.9 %) by heterogeneous atmospheric deposition (q>0.254) co-influenced by the terrains and soil properties. Highly heterogeneous sources are also noteworthy for their potential to pose extreme risks (THI=1.122) in local areas. This study highlights the necessity of integrating spatial heterogeneity in pollution and risk assessment of soil TEs.

Keyword:

Geodetector model Positive matrix factorization Source-oriented risks Spatial heterogeneity Source apportionment

Author Community:

  • [ 1 ] [Zhu, Guanhua]Beijing Normal Univ, Coll Water Sci, Beijing 100875, Peoples R China
  • [ 2 ] [Tong, Baocai]Beijing Normal Univ, Coll Water Sci, Beijing 100875, Peoples R China
  • [ 3 ] [Zhai, Yuanzheng]Beijing Normal Univ, Coll Water Sci, Beijing 100875, Peoples R China
  • [ 4 ] [Chen, Haiyang]Beijing Normal Univ, Coll Water Sci, Beijing 100875, Peoples R China
  • [ 5 ] [Zhu, Ganghui]Minist Ecol & Environm Peoples Republ China, Tech Ctr Soil Agr & Rural Ecol & Environm, Beijing 100012, Peoples R China
  • [ 6 ] [Zhang, Dasheng]Hebei Inst Water Sci, Shijiazhuang 050051, Peoples R China
  • [ 7 ] [Wu, Jin]Beijing Univ Technol, Fac Architecture Civil & Transportat Engn, Beijing 100124, Peoples R China

Reprint Author's Address:

  • [Zhai, Yuanzheng]Beijing Normal Univ, Coll Water Sci, Beijing 100875, Peoples R China;;[Chen, Haiyang]Beijing Normal Univ, Coll Water Sci, Beijing 100875, Peoples R China;;

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Source :

JOURNAL OF HAZARDOUS MATERIALS

ISSN: 0304-3894

Year: 2024

Volume: 479

1 3 . 6 0 0

JCR@2022

Cited Count:

WoS CC Cited Count: 1

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 8

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