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Author:

Wu, L. (Wu, L..) | Pan, Y. (Pan, Y..) | Zhang, Y. (Zhang, Y..) | Geng, Y. (Geng, Y..) | Cao, J. (Cao, J..) | Su, X. (Su, X..) | Xu, J. (Xu, J..) | Xie, H. (Xie, H..) | Gao, D. (Gao, D..)

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EI Scopus SCIE

Abstract:

Violet-emitting perovskite quantum dots (QDs) are of great significance for theoretical and experimental research aimed at promoting the development of environmentally friendly violet light-emitting diodes (LEDs). Nevertheless, the synthesis of violet perovskite QDs via ligand-assisted reprecipitation is challenging due to the significant bandgap. A simple and economical cryo-bonding ligand-assisted reprecipitation (Cb-LARP) method is proposed as a means of synthesizing deep violet lead-free organic-inorganic hybrid perovskite (OIHP) QDs, with the objective of increasing the bandgap in the material. The MA3Bi2Br9 QDs synthesized by the Cb-LARP method exhibit bright violet luminescence at 400 nm, with a PLQY of 50.1%. Moreover, the photoluminescence peak of the QDs can be adjusted from 402 to 393 nm by modifying the final reaction time. It is noteworthy that the MA3Bi2Br6Cl3 QDs exhibited ultraviolet emission at 379 nm, corresponding to a PLQY of 35.4%. Similarly, the emission peak of the QDs can be tuned from 379 to 376 nm by changing the final reaction time. The results demonstrate that the deep violet emitting OIHP QDs have been successfully synthesized. This study provides a theoretical reference for short-wavelength perovskite materials and an experimental reference for the study of violet and UV quantum-dot light-emitting diode devices. © 2024 Wiley-VCH GmbH.

Keyword:

Cb-LARP perovskite structure quantum dots ultraviolet light

Author Community:

  • [ 1 ] [Wu L.]College of Science, Xi'an University of Architecture and Technology, Xi'an, 710055, China
  • [ 2 ] [Pan Y.]College of Science, Xi'an University of Architecture and Technology, Xi'an, 710055, China
  • [ 3 ] [Pan Y.]Institute of Advanced Optics and Quantum Devices, Xi'an University of Architecture and Technology, Xi'an, 710055, China
  • [ 4 ] [Zhang Y.]College of Science, Xi'an University of Architecture and Technology, Xi'an, 710055, China
  • [ 5 ] [Geng Y.]College of Science, Xi'an University of Architecture and Technology, Xi'an, 710055, China
  • [ 6 ] [Geng Y.]Institute of Advanced Optics and Quantum Devices, Xi'an University of Architecture and Technology, Xi'an, 710055, China
  • [ 7 ] [Cao J.]College of Science, Xi'an University of Architecture and Technology, Xi'an, 710055, China
  • [ 8 ] [Cao J.]Institute of Advanced Optics and Quantum Devices, Xi'an University of Architecture and Technology, Xi'an, 710055, China
  • [ 9 ] [Su X.]College of Applied Sciences, Beijing University of Technology, Beijing, 100124, China
  • [ 10 ] [Xu J.]College of Science, Xi'an University of Architecture and Technology, Xi'an, 710055, China
  • [ 11 ] [Xu J.]Key Laboratory for Physical Electronics and Devices of the Ministry of Education & Shaanxi Key Lab of Information Photonic Technique, School of Electronic and Information Engineering, Xi'an Jiaotong University, No.28, Xianning West Road, Xi'an, 710049, China
  • [ 12 ] [Xie H.]College of Science, Xi'an University of Architecture and Technology, Xi'an, 710055, China
  • [ 13 ] [Xie H.]Key Laboratory for Physical Electronics and Devices of the Ministry of Education & Shaanxi Key Lab of Information Photonic Technique, School of Electronic and Information Engineering, Xi'an Jiaotong University, No.28, Xianning West Road, Xi'an, 710049, China
  • [ 14 ] [Gao D.]School of Mathematics and Physics, North China Electric Power University, Beijing, 102206, China

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Source :

Advanced Functional Materials

ISSN: 1616-301X

Year: 2024

Issue: 7

Volume: 35

1 9 . 0 0 0

JCR@2022

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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