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Author:

Zhang, Xinyou (Zhang, Xinyou.) | Guo, Wei (Guo, Wei.) | Du, Linzhu (Du, Linzhu.) | Yue, Junhui (Yue, Junhui.) | Wang, Binyu (Wang, Binyu.) | Li, Jun (Li, Jun.) | Wang, Shuhang (Wang, Shuhang.) | Xia, Jiang (Xia, Jiang.) | Wu, Zhihao (Wu, Zhihao.) | Zhao, Xu (Zhao, Xu.) | Gao, Yue (Gao, Yue.)

Indexed by:

Scopus SCIE

Abstract:

In the soil environment, microplastics (MPs) commonly coexist with organic pollutants such as nonylphenol (NP), affecting the migration of NP through adsorption/desorption. However, few studies have focused on the interaction between NP and MPs in soil, especially for MPs of different types and ageing characteristics. In this study, non-polar polypropylene (PP) and polar polyamide (PA) MPs were aged either photochemically (144 h) or within soil (60 days), then used to determine the effect of 5 % MPs on the adsorption behaviour of NP (0.1-4.0 mg/L) in soil. Results showed that both ageing processes significantly promoted the conversion of -CH3 groups to C-O and C--O on the surface of PPMPs, while PAMPs exhibited amide groups changes and a reduction in average particle size due to ageing. Additionally, both ageing processes promoted the adsorption of NP by soil containing PPMPs, due to an increase in oxygen-containing functional groups and specific surface area. In contrast, the NP adsorption capacity of soil containing PAMPs decreased by 15.4 % following photochemical ageing due to hydrolysis of amide groups, but increased by 21.15 % after soil ageing due to reorganization of amide groups, respectively. The soil-PAMPs systems exhibited a stronger affinity for NP compared to the soilPPMPs systems, which was primarily attributed to the dominant role of hydrogen bonding. NP was found to be distributed mainly on soil particles in the soil-PPMPs systems, while it tended to be adsorbed by MPs in the soil-PAMPs systems, especially in the soil aged MPs system. This study provides a comprehensive analysis of the complex effects of MPs on coexisting pollutants in soil environments, highlighting the effect of MP characteristics on the adsorption of organic pollutants, which is essential for understanding the transport behaviour of organic pollutants.

Keyword:

Polyamide Polypropylene Nonylphenol Ageing process Polarity Adsorption behaviour

Author Community:

  • [ 1 ] [Zhang, Xinyou]Beijing Univ Technol, Coll Architecture & Civil Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Guo, Wei]Beijing Univ Technol, Coll Architecture & Civil Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Du, Linzhu]Beijing Univ Technol, Coll Architecture & Civil Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Yue, Junhui]Beijing Univ Technol, Coll Architecture & Civil Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Wang, Binyu]Beijing Univ Technol, Coll Architecture & Civil Engn, Beijing 100124, Peoples R China
  • [ 6 ] [Li, Jun]Beijing Univ Technol, Coll Architecture & Civil Engn, Beijing 100124, Peoples R China
  • [ 7 ] [Wang, Shuhang]Chinese Res Acad Environm Sci CRAES, Inst Lake Environm, State Environm Protect Key Lab Lake Pollut Control, Beijing 100012, Peoples R China
  • [ 8 ] [Xia, Jiang]Chinese Res Acad Environm Sci CRAES, Inst Lake Environm, State Environm Protect Key Lab Lake Pollut Control, Beijing 100012, Peoples R China
  • [ 9 ] [Wu, Zhihao]Chinese Res Acad Environm Sci CRAES, Inst Lake Environm, State Environm Protect Key Lab Lake Pollut Control, Beijing 100012, Peoples R China
  • [ 10 ] [Zhao, Xu]Shandong Univ, Inst Blue & Green Dev, Weihai 264209, Peoples R China
  • [ 11 ] [Gao, Yue]Vrije Univ Brussel VUB, Analyt Environm & Geochem AMGC, B-1050 Ixelles, Belgium

Reprint Author's Address:

  • [Guo, Wei]Beijing Univ Technol, Pingleyuan 100, Chaoyang 100124, Beijing, Peoples R China;;

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Source :

ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY

ISSN: 0147-6513

Year: 2024

Volume: 287

6 . 8 0 0

JCR@2022

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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