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Author:

Zou, Bolin (Zou, Bolin.) | Kim, Semi (Kim, Semi.) | Zhang, Xingyu (Zhang, Xingyu.) | Chang, Qiang (Chang, Qiang.) | Ping, Weiwei (Ping, Weiwei.) | Jeong, Daeun (Jeong, Daeun.) | Ge, Binghui (Ge, Binghui.) | Liao, Xingqi (Liao, Xingqi.) | Huang, Zhimei (Huang, Zhimei.) | Kim, Juyeong (Kim, Juyeong.) | Feng, Xuyong (Feng, Xuyong.) | Xiang, Hongfa (Xiang, Hongfa.) | Song, Xiaohui (Song, Xiaohui.)

Indexed by:

EI Scopus SCIE

Abstract:

Metal-organic frameworks (MOFs) offer versatile building blocks for high-performance materials across practical applications. Crystallization studies reveal MOF complex pathways crucial for biological and synthetic systems, yet understanding remains incomplete. Here, we employ in-situ liquid phase transmission electron microscopy (LPTEM) to scrutinize the growth dynamics of ZIF-8 in colloidal environments, aiming to deepen our comprehension of MOF crystallization. This study employs in-situ LPTEM to investigate ZIF-8 nanoparticle growth, revealing the combination of classical and non-classical nucleation processes in the same batch leading a challenge to control nanoparticle morphology and size, while heterogeneous nucleation is dominant giving monodispersed nanoparticle at the presence of ZIF-8 seeds in mother solution. Additionally, integrating MOF-derived carbon materials in lithium-ion batteries (LIBs) faces challenges in achieving high-performance, controllable Ndoping and long-term stability. Ultrafast high-temperature sintering (UHS) is utilized to carbonize ZIF-8, regulating N-doping hard carbon with Zn single atoms doping. Results show optimal morphology at 800 degrees C for 20 s, yielding higher concentration of Zn-doping, higher N-doping levels, and good conductivity compared to conventional sintering in tube furnace. LIB tests demonstrate exceptional cycling performance and stability across wide temperatures. This UHS strategy for ZIF-8 contributes to establishing a balance between Zn-N-doping and the degree of graphitization, thus providing an interdisciplinary approach that offers efficient MOF derivative synthesis for promising wide temperature range applications of LIBs.

Keyword:

ZIF-8 Wide temperature range Ultrafast high-temperature sintering in-situ liquid phase TEM Dual-doping

Author Community:

  • [ 1 ] [Zou, Bolin]Hefei Univ Technol, Sch Mat Sci & Engn, Hefei 230009, Anhui, Peoples R China
  • [ 2 ] [Chang, Qiang]Hefei Univ Technol, Sch Mat Sci & Engn, Hefei 230009, Anhui, Peoples R China
  • [ 3 ] [Ping, Weiwei]Hefei Univ Technol, Sch Mat Sci & Engn, Hefei 230009, Anhui, Peoples R China
  • [ 4 ] [Huang, Zhimei]Hefei Univ Technol, Sch Mat Sci & Engn, Hefei 230009, Anhui, Peoples R China
  • [ 5 ] [Feng, Xuyong]Hefei Univ Technol, Sch Mat Sci & Engn, Hefei 230009, Anhui, Peoples R China
  • [ 6 ] [Xiang, Hongfa]Hefei Univ Technol, Sch Mat Sci & Engn, Hefei 230009, Anhui, Peoples R China
  • [ 7 ] [Song, Xiaohui]Hefei Univ Technol, Sch Mat Sci & Engn, Hefei 230009, Anhui, Peoples R China
  • [ 8 ] [Kim, Semi]Gyeongsang Natl Univ, Res Inst Nat Sci, Dept Chem, Jinju 52828, South Korea
  • [ 9 ] [Jeong, Daeun]Gyeongsang Natl Univ, Res Inst Nat Sci, Dept Chem, Jinju 52828, South Korea
  • [ 10 ] [Kim, Juyeong]Gyeongsang Natl Univ, Res Inst Nat Sci, Dept Chem, Jinju 52828, South Korea
  • [ 11 ] [Zhang, Xingyu]Beijing Univ Technol, Sch Math Stat & Mech, Beijing 100124, Peoples R China
  • [ 12 ] [Ge, Binghui]Anhui Univ, Inst Phys Sci & Informat Technol, Informat Mat & Intelligent Sensing Lab Anhui Prov, Hefei 230601, Peoples R China
  • [ 13 ] [Liao, Xingqi]Harbin Inst Technol, Inst Adv Ceram, Sch Mat Sci & Engn, Harbin 150080, Peoples R China
  • [ 14 ] [Feng, Xuyong]Hefei Univ Technol, Engn Res Ctr High Performance Copper Alloy Mat & P, Minist Educ, Hefei 230009, Peoples R China
  • [ 15 ] [Xiang, Hongfa]Hefei Univ Technol, Engn Res Ctr High Performance Copper Alloy Mat & P, Minist Educ, Hefei 230009, Peoples R China
  • [ 16 ] [Song, Xiaohui]Hefei Univ Technol, Engn Res Ctr High Performance Copper Alloy Mat & P, Minist Educ, Hefei 230009, Peoples R China

Reprint Author's Address:

  • [Song, Xiaohui]Hefei Univ Technol, Engn Res Ctr High Performance Copper Alloy Mat & P, Minist Educ, Hefei 230009, Peoples R China

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Source :

CHEMICAL ENGINEERING JOURNAL

ISSN: 1385-8947

Year: 2024

Volume: 502

1 5 . 1 0 0

JCR@2022

Cited Count:

WoS CC Cited Count: 1

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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