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Abstract:
SBS-modified high viscosity asphalt (SMHVA) was the core binding material for constructing ecological porous asphalt pavements (PAP). However, the porous structures of PAP made SMHVA susceptible to fatigue damage and aging degradation damage during actual use. To improve the damage-repairing performance of SMHVA, this study developed a novel self-reinforcing chemical modifier (SRCM). The primary component of SRCM was isophorone diisocyanate (IPDI), with chemically blocked active isocyanate groups (-NCO), providing excellent reaction controllability and chemical repairing performance. Additionally, dynamic disulfide bonds were specifically introduced into the SRCM molecular structure to further enhance its dynamic structure repairing performance. Firstly, SRCM was applied to modify SMHVA prepared chemically modified SMHVA (CSMHVA). Infrared spectroscopy and fluorescence microscopy revealed that the high-temperature conditions during SMHVA preparation triggered the terminal-NCO reactive compounds released from SRCM, facilitating its cross-linking reactions with asphalt. During short-term aging, the continuously activated SRCM healed the degraded SBS molecular structure and effectively established dynamic cross-linking networks, thereby achieving self-enhancement of the SBS network, making the SBS cross-linking network main chains of CSMHVA almost complete after aging. Rotational viscosity tests revealed that the reaction between activated SRCM and asphalt produced carbon dioxide bubbles and dynamic covalent structure, which lowered the optimal mixing and compaction temperatures of CSMHVA by 8.1 °C and 4.2 °C, respectively. Rheological master curve analysis indicated that adding SRCM improved both the high and low-temperature performance of SMHVA, and the sustained effect of SRCM further enhanced the high-frequency (low-temperature) performance of SMHVA after short-term aging. MSCR tests and time sweep results confirmed that SRCM significantly improved high-temperature rheological performance, and the dynamic SBS cross-linking networks formed during aging decreased CSMHVA's aging sensitivity. The results can provide more environmentally friendly material options for the asphalt industry. © 2024 Elsevier Ltd
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Construction and Building Materials
ISSN: 0950-0618
Year: 2025
Volume: 458
7 . 4 0 0
JCR@2022
Cited Count:
SCOPUS Cited Count: 1
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 8
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