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Photocatalysis-ultrafiltration is potentially considered to be one of the effective technologies for the advanced treatment of algae-laden water. However, the problems of nano-photocatalyst loss and membrane fouling during continuous operation greatly limit its practical application. Herein, a novel integrated photocatalysis-ultrafiltration (PC-UF) reactor, including a photocatalytic zone, a separation and reflux zone of the nano-photocatalyst of Bi2O3–TiO2/PAC (Bi-doped TiO2 nano-composites supported by powdered activated carbon) and an ultrafiltration zone was developed. The operating parameters of the PC-UF reactor were optimized, and the stability of PC-UF continuous operation as well as the mechanism of the decontamination and membrane fouling control were investigated. The results indicated that the PC-UF reactor was continuously operated for 63 d under the optimal conditions (Bi2O3–TiO2/PAC dosage of 1.0 g/L, UV lamp power of 12 W, aeration rate of 200 mL/min, hydraulic retention time of 4 h, membrane flux of 30 LMH, backwashing frequency of once every 90 min for 1 min), and no obvious loss of nano-photocatalyst was found. The average removal of UV254, DOC and turbidity was stable at 61.3 %, 47.5 % and 92.5 %. Photocatalysis mainly photo-degraded tryptophan, fulvic acid and humic substances fluorescent components, decomposed and mineralized organic matter with molecular weights of 10–5000 Da, and ultrafiltration mainly removed microbial metabolites and humic substances. Photocatalysis altered foulants properties by decomposing phenols, amines, and aldehydes, thereby reducing foulants-membrane attraction and converting foulant-foulant attraction into repulsion, thereby mitigating membrane fouling. This work provides new ideas for the development of integrated PC-UF equipment and their continuous operation. © 2024 Elsevier B.V.
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Journal of Membrane Science
ISSN: 0376-7388
Year: 2025
Volume: 717
9 . 5 0 0
JCR@2022
Cited Count:
SCOPUS Cited Count: 1
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 8
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