The　separation　and　removal　of　nutrient　salts　from　wastewater　can　realize　environmental　remediation,　and　resource　recycling　and　utilization.　Electrodialysis　(ED)　membrane　separation　technology　can　offer　an　effective　and　low-energy　consumption　alternative　but　requires　selective　separation　of　nutrient　salts　with　rapid　anions　permeation　rate.　We　fabricated　selective　anion　exchange　membranes　(PA-ATG)　with　the　polyamide　(PA)　surface　modification　of　commercial　ATG　anion　exchange　membrane　by　interfacial　polymerization　(IP)　method.　The　dense　PA　thin-film　layer　with　high　hydrophilicity　and　electronegativity　facilitates　nitrate/phosphate　anions　selectively　permeating　through　the　PA-ATG　membrane.　The　PA-ATG　membrane　exhibited　a　NO3−　anion　permeation　rate　of　1.1　mol　m−2　h−1　and　good　NO3−/HxPO4(3−x)-　permselectivity　of　2.02,　which　is　∼2.0　times　higher　than　that　of　the　pristine　ATG　membrane.　Owing　to　the　rigid　aromatic　crosslinking　structure,　and　electrostatic　and　hydrogen-bonding　multiple　interfacial　interaction,　the　as-prepared　membrane　PA-ATG　showed　good　stable　and　efficient　separation　performance　during　ED　process　for　the　nutrient　wastewater　treatment.　©　2024　Elsevier　B.V.