Electrophotochemical　ligand-to-metal　charge　transfer　(LMCT)　catalysis　has　contributed　to　advancing　sustainable　radical　chemistry　by　exploiting　both　visible　light　and　electricity　as　clean　energy　inputs.　Moreover,　electrophotochemical　LMCT　catalysis　is　not　only　beneficial　for　selective　activation　of　metal-bound　ligands　even　in　the　presence　of　more　electron-rich　moieties,　but　also　exhibits　high　functional　group　compatibility　due　to　the　low　operating　potentials　resulting　from　the　inherent　inner-sphere　reactivity　mode.　Here　we　highlight　the　advancements　in　the　field　of　electrophotochemical　LMCT　catalysis,　with　an　emphasis　on　the　substrate　scope,　reaction　limitations　as　well　as　mechanistic　insights.　At　the　end　of　this　review,　we　provide　our　views　on　current　challenges　and　future　potential　opportunities　in　this　emerging　field.