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Author:

Zhang, Ao (Zhang, Ao.) | Liu, Meng (Liu, Meng.) | Feng, Xiangrui (Feng, Xiangrui.) | Liu, Shuo (Liu, Shuo.) | Zhang, Yongzheng (Zhang, Yongzheng.) | Huang, Jinbiao (Huang, Jinbiao.) | Ma, Jiang (Ma, Jiang.) | Zhou, Kailing (Zhou, Kailing.) | Liu, Jingbing (Liu, Jingbing.) | Lu, Zhen (Lu, Zhen.) | Wang, Hao (Wang, Hao.)

Indexed by:

Scopus SCIE

Abstract:

Non-enzymatic electrochemical glucose sensors, representing the fourth generation of glucose sensors, exhibit significant advantages including high response speed, resistance to biofouling, low cost, and ease of preparation. However, current glucose sensing materials face challenges such as high detection limits and poor anti-interference performance, which limit their practical applications. Herein, we have developed an innovative catalyst composed of Cu(OH)2 nanograsses decorated on a bimetallic nanoporous structure through a simple two-step oxidation method. The resulting catalyst forms a unique sandwich-like structure, where Cu(OH)2 nanograsses with hierarchical morphologies uniformly grow both on the external surface and within the porous channels of nanoporous CuAg. This configuration ensures the full utilization of the high specific surface area and thereby provides a high concentration of active sites, contributing to excellent catalytic performance for glucose oxidation. This developed composite catalyst demonstrates an ultra-low detection limit of 100 nM, a high sensitivity of approximately 5.16 mA mM-1 cm-2, a wide linear response range up to 8 mM, and excellent anti-interference ability. These outstanding electrocatalytic properties arise from the synergistic effect of the nanoporous CuAg's excellent conductivity and mass transfer capabilities, combined with the multiple active sites of the in situ-grown hierarchical Cu(OH)2 nanograsses. This work highlights a unique approach to designing glucose oxidation catalysts with remarkable electrocatalytic performance, utilizing a straightforward two-step oxidation method to assemble hierarchical hydroxide morphologies, offering a promising avenue for the practical application of advanced glucose sensors.

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Author Community:

  • [ 1 ] [Zhang, Ao]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Zhou, Kailing]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Liu, Jingbing]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Wang, Hao]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Zhang, Ao]Chinese Acad Sci, Inst Phys, Beijing 100190, Peoples R China
  • [ 6 ] [Liu, Meng]Chinese Acad Sci, Inst Phys, Beijing 100190, Peoples R China
  • [ 7 ] [Feng, Xiangrui]Chinese Acad Sci, Inst Phys, Beijing 100190, Peoples R China
  • [ 8 ] [Lu, Zhen]Chinese Acad Sci, Inst Phys, Beijing 100190, Peoples R China
  • [ 9 ] [Liu, Meng]Qufu Normal Univ, Sch Phys & Phys Engn, Qufu 273165, Peoples R China
  • [ 10 ] [Feng, Xiangrui]Qufu Normal Univ, Sch Phys & Phys Engn, Qufu 273165, Peoples R China
  • [ 11 ] [Liu, Shuo]Qufu Normal Univ, Sch Phys & Phys Engn, Qufu 273165, Peoples R China
  • [ 12 ] [Zhang, Yongzheng]Qufu Normal Univ, Sch Phys & Phys Engn, Qufu 273165, Peoples R China
  • [ 13 ] [Huang, Jinbiao]Shenzhen Univ, Coll Mechatron & Control Engn, Shenzhen 518060, Peoples R China
  • [ 14 ] [Ma, Jiang]Shenzhen Univ, Coll Mechatron & Control Engn, Shenzhen 518060, Peoples R China
  • [ 15 ] [Lu, Zhen]Univ Chinese Acad Sci, Sch Phys Sci, Beijing 100049, Peoples R China

Reprint Author's Address:

  • [Zhou, Kailing]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China;;[Lu, Zhen]Chinese Acad Sci, Inst Phys, Beijing 100190, Peoples R China;;[Lu, Zhen]Univ Chinese Acad Sci, Sch Phys Sci, Beijing 100049, Peoples R China

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Source :

JOURNAL OF MATERIALS CHEMISTRY A

ISSN: 2050-7488

Year: 2025

1 1 . 9 0 0

JCR@2022

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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