Palladium-nickel(Pd-Ni)bimetallic　composite　electrodes　were　fabricated　on　meshed　titanium(Ti)substrates　by　electrochemical　deposition　in　the　presence　of　polymeric　pyrrole(PPy),　PPy-cetyl　trimethyl　ammonium　bromide(CTAB),　PPy-sodium　dodecyl　sulphate(SDS),　PPy-sodium　dodecyl　sulfonate(SLS),　respectively(Pd-Ni/PPy/Ti　electrode,　Pd-Ni(CTAB)/PPy/Ti　electrode,　Pd-Ni(SDS)/PPy/Ti　electrode　and　Pd-Ni(SLS)/PPy/Ti　electrode).　The　different　surfactant　effects　on　electrochemical　catalytic　activities　were　studied.　Cyclic　voltammetry(CV)showed　that　the　hydrogen　adsorption　peak　values　of　the　four　electrodes　were　-93,　-116,　-70,　-82mA,　respectively,　which　indicated　that　the　Pd-Ni(CTAB)/PPy/Ti　electrode　had　best　electrochemical　catalytic　activity.　Scanning　electron　microscope(SEM)images　revealed　the　effects　of　different　surfactants　on　the　surface　morphology　of　electrodes.　The　quantities　of　Pd　and　Ni　on　the　four　electrodes　were　analyzed　by　means　of　inductively　coupled　plasma-atomic　emission　spectrometry(ICP-AES).　The　results　of　X-ray　diffraction(XRD)showed　that　four　electrode　films　were　made　of　Pd-Ni　alloy.　Experimental　results　indicated　that　the　Pd-Ni　bimetallic　composite　electrode　doped　cationic　surfactant　CTAB　had　good　electrochemical　performance　and　high　potential　of　reductive　dechlorination.