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Author:

Ji, Chang-Wei (Ji, Chang-Wei.) (Scholars:纪常伟) | Dai, Xiao-Xu (Dai, Xiao-Xu.) | Liang, Chen (Liang, Chen.) | Wang, Shuo-Feng (Wang, Shuo-Feng.) | Zhang, Xu (Zhang, Xu.) | Fan, Bo-Yuan (Fan, Bo-Yuan.)

Indexed by:

EI Scopus PKU CSCD

Abstract:

Stream reforming ethanol can not only produce hydrogen on board and solve the problem of storage, but also realize the mixed combustion of fuel with hydrogen-rich reformed gas and improve engine emissions. To get the optimal experiment method, the experiment was performed on a self-designed apparatus that could provide the similar temperature as the engine exhaust gas. The effects of reaction temperature, water/ethanol molar ratio and gas hourly space velocity (GHSV) on hydrogen concentration in the outlet gases were experimentally investigated over Cu49Zn21Al18Zr12 and Pt/CZO/Al2O3 catalyst. Results show that hydrogen productivity through steam reforming of ethanol over Pt/CZO/Al2O3 catalyst is higher than Cu49Zn21Al18Zr12 catalyst, especially when the reaction temperature is up to 823 K. The average values of hydrogen concentration are 40.26% and 47.78% when the reaction temperature ranges from 723 K to 973 K, GHSV is 720 h-1, water/ethanol molar ratio are 6:1 and 4:1, respectively. However, as the Cu49Zn21Al18Zr12 catalyst gains a relatively higher productivity over 873 K and lower cost than Pt/CZO/Al2O3 catalyst, steam reforming of ethanol over Cu49Zn21Al18Zr12 catalyst may become a promising and practical way for producing hydrogen on vehicles.

Keyword:

Aluminum alloys Hydrogen Zinc alloys Steam Hydrogen storage Molar ratio Steam reforming Copper Catalysts Platinum alloys Productivity Hydrogen production Molar concentration Zircaloy Gas emissions Ethanol Engines Hydrogen fuels Copper alloys

Author Community:

  • [ 1 ] [Ji, Chang-Wei]College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 2 ] [Dai, Xiao-Xu]College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 3 ] [Liang, Chen]College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 4 ] [Wang, Shuo-Feng]College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 5 ] [Zhang, Xu]College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 6 ] [Fan, Bo-Yuan]College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China

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Source :

Journal of Beijing University of Technology

ISSN: 0254-0037

Year: 2012

Issue: 6

Volume: 38

Page: 904-909

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 10

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