• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
搜索

Author:

Huang, Kelin (Huang, Kelin.) | Wu, Rui (Wu, Rui.) | Li, Huiquan (Li, Huiquan.) | Cao, Yan (Cao, Yan.) | Wang, Jinshu (Wang, Jinshu.) (Scholars:王金淑)

Indexed by:

EI Scopus PKU CSCD

Abstract:

Using ionic liquid 1-allyl-3-methylimidazolium chloride (AmimCl)as reaction media, microcrystalline cellulose as raw material, the kinetics of homogeneous acylation of cellulose in ionic liquid was studied. The effect of initial cellulose hydroxyl concentration from 0.21 mol·L-1 to 0.85 mol·L-1 and temperatures from 353 K to 373 K on the acylation rate were measured. Results showed that the acylation rate increases with increasing initial cellulose hydroxyl concentration and reaction temperatures. The reaction kinetic equations were determined based on the experimental data. The reaction order for both acylation by acetic anhydride and by mixture of butyric anhydride and acetic anhydride is first-order, and their apparent activation energies are 19.03 kJ·mol-1 and 20.04 kJ·mol-1 respectively. © All Rights Reserved.

Keyword:

Acylation Ionic liquids Activation energy Enzyme kinetics Integral equations Cellulose Kinetics Chlorine compounds Reaction kinetics

Author Community:

  • [ 1 ] [Huang, Kelin]College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 2 ] [Huang, Kelin]Guangxi Branch of China Academy of Science and Technology Development, Nanning 530022, Guangxi, China
  • [ 3 ] [Huang, Kelin]Guangxi Research Institute of Chemical Industry, Nanning 530001, Guangxi, China
  • [ 4 ] [Wu, Rui]Chemistry and Ecological Engineering College, Guangxi University for Nationalities, Nanning 530006, China
  • [ 5 ] [Li, Huiquan]Institute of Process Engineering, Chinese Acad. of Sci., Beijing 100190, China
  • [ 6 ] [Cao, Yan]Institute of Process Engineering, Chinese Acad. of Sci., Beijing 100190, China
  • [ 7 ] [Wang, Jinshu]College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China

Reprint Author's Address:

Show more details

Related Keywords:

Source :

CIESC Journal

ISSN: 0438-1157

Year: 2011

Issue: 7

Volume: 62

Page: 1898-1905

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

Online/Total:1290/10567903
Address:BJUT Library(100 Pingleyuan,Chaoyang District,Beijing 100124, China Post Code:100124) Contact Us:010-67392185
Copyright:BJUT Library Technical Support:Beijing Aegean Software Co., Ltd.