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Author:

Li, Yang-Chao (Li, Yang-Chao.) | Zhang, Ming (Zhang, Ming.) | Dong, Guo-Bo (Dong, Guo-Bo.) | Zhao, Xue-Ping (Zhao, Xue-Ping.) | Yan, Hui (Yan, Hui.)

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Abstract:

A series of CuCr1-xMgxO2 (0≤x≤0.09) thin films were deposited on quartz substrates using radio frequency magnetron sputtering. The structures, optical and electrical properties of CuCr0.91Mg0.09O2 thin films were investigated by diffractometry, double-beam spectrophotometry, electrical property measurement, respectively. XRD pattern indicates that all films are of 3R polycrystalline delafossite phase with good crystallinity after annealing. The conductivity of film has a notable improvement with increasing Mg. The conductivity at room temperature is 6.16×10-2 S/cm for x=0.09 which is nearly 400 times higher than that undoped CuCrO2 film. The p-type nature of films is confirmed by Hall measurements. The temperature dependence of electrical conductivity agrees well with the Arrhenius rule in the range of 200-300 K for all samples, and the minimum activation energy is 0.034 eV with x=0.09. Both average transmittance and optical band gap of CuCr1-xMgxO2 films decrease with the increase of Mg concentration.

Keyword:

Chromium compounds Magnetron sputtering Energy gap Copper compounds Activation energy Thin films Optical band gaps Optical properties Crystallinity Optical films Temperature distribution

Author Community:

  • [ 1 ] [Li, Yang-Chao]College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 2 ] [Zhang, Ming]College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 3 ] [Dong, Guo-Bo]College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 4 ] [Zhao, Xue-Ping]College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 5 ] [Yan, Hui]College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China

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Source :

Chinese Journal of Nonferrous Metals

ISSN: 1004-0609

Year: 2010

Issue: 5

Volume: 20

Page: 898-902

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 8

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