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Author:

Wei, Qiumei (Wei, Qiumei.) | Zhu, Mankang (Zhu, Mankang.) | Zheng, Mupeng (Zheng, Mupeng.) | Hou, Yudong (Hou, Yudong.) (Scholars:侯育冬) | Li, Junjie (Li, Junjie.) | Bai, Yang (Bai, Yang.)

Indexed by:

EI Scopus SCIE

Abstract:

Here, we show the large electrocaloric effect near room temperature in ergodic relaxor (Bi1/2Na1/2)(0.93)Sa(0.07) (Zn1/3Nb2/3)(0.01)Ti0.99O3 (BNBZN) observed by a modified differential scanning calorimeter. Microstructure analysis revealed that BNBZN sample demonstrates global pseudocubic structure with locally distorted structures. Electric measurements showed that the sample coexists of two types of polar nanoregions (PNRs) with different coupling ability, and behaves as ergodic relaxor near room temperature. Due to the transition between two types of PNRs around 40 degrees C, large adiabatic temperature change of 1.04 degrees C with high electrocaloric strength of 2.1 x 10(-7) degrees C.m/V was recorded, indicating its promising prospect for solid-state refrigeration application. (C) 2019 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Keyword:

Electrocaloric effect Bi0.5Na0.5TiO3 Direct method Lead-free ferroelectrics Ergodic relaxor

Author Community:

  • [ 1 ] [Wei, Qiumei]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Zhu, Mankang]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Zheng, Mupeng]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Hou, Yudong]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Li, Junjie]Univ Sci & Technol Beijing, Minist Educ, Key Lab Environm Fracture, Beijing Adv Innovat Ctr Mat Genome Engn, Beijing 100083, Peoples R China
  • [ 6 ] [Bai, Yang]Univ Sci & Technol Beijing, Minist Educ, Key Lab Environm Fracture, Beijing Adv Innovat Ctr Mat Genome Engn, Beijing 100083, Peoples R China

Reprint Author's Address:

  • [Zhu, Mankang]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China;;[Bai, Yang]Univ Sci & Technol Beijing, Minist Educ, Key Lab Environm Fracture, Beijing Adv Innovat Ctr Mat Genome Engn, Beijing 100083, Peoples R China

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Source :

SCRIPTA MATERIALIA

ISSN: 1359-6462

Year: 2019

Volume: 171

Page: 10-15

6 . 0 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:211

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count: 28

SCOPUS Cited Count: 27

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 11

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