• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
搜索

Author:

Zhang, Xin (Zhang, Xin.) | Zhang, Jiuxing (Zhang, Jiuxing.) | Lu, Qingmei (Lu, Qingmei.) | Wei, Qun (Wei, Qun.) | Liu, Danmin (Liu, Danmin.) (Scholars:刘丹敏) | Liu, Yanqin (Liu, Yanqin.)

Indexed by:

EI Scopus PKU CSCD

Abstract:

The filled skutterudite compounds REy(Fe/Ni)xCo4-xSb12 (x=0-1.0, y=0-0.4) were synthesized by solid state reaction and Spark Plasma Sintering (SPS) at 800-1000 K using the powders of Co, Sb, Fe, Ni and rare earth Ce and La as precursors. The effects of the kinds of filling and replacement atoms and the form of filling on the lattice thermal conductivity and thermo-electric property were discussed in this paper. The results indicate that the thermoconductivity is remarkably reduced by substituting Co with Ni and Fe, and Ni has a better effect on thermoconductivity in contrast with Fe. In addition, the lattice thermal conductivity is obviously decreased by filling with rare earth Ce and La into the Skutterudite structure. The decrease of lattice thermal conductivity is more effective by double fillings of Ce and La than single filling for the same filling fraction. The electric conductivity is decreasing and the Seebeck coefficient is increasing with the filling fraction of Ce and La increasing. The Skutterudite compound Ce0.1La0.2FeCo3Sb12 possesses the minimum thermal conductivity and the highest Seebeck coefficient with the highest ZT value of 0.6 at 800 K.

Keyword:

Seebeck coefficient Substitution reactions Thermal conductivity Synthesis (chemical) Spark plasma sintering Thermoelectricity Rare earth elements Solid state reactions

Author Community:

  • [ 1 ] [Zhang, Xin]Beijing University of Technology, Beijing 100022, China
  • [ 2 ] [Zhang, Jiuxing]Beijing University of Technology, Beijing 100022, China
  • [ 3 ] [Lu, Qingmei]Beijing University of Technology, Beijing 100022, China
  • [ 4 ] [Wei, Qun]Beijing University of Technology, Beijing 100022, China
  • [ 5 ] [Liu, Danmin]Beijing University of Technology, Beijing 100022, China
  • [ 6 ] [Liu, Yanqin]Beijing University of Technology, Beijing 100022, China

Reprint Author's Address:

Show more details

Related Keywords:

Source :

Rare Metal Materials and Engineering

ISSN: 1002-185X

Year: 2007

Issue: 6

Volume: 36

Page: 968-972

0 . 7 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

JCR Journal Grade:3

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

Online/Total:1283/10605445
Address:BJUT Library(100 Pingleyuan,Chaoyang District,Beijing 100124, China Post Code:100124) Contact Us:010-67392185
Copyright:BJUT Library Technical Support:Beijing Aegean Software Co., Ltd.