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Electrocatalyst for oxygen-reduction reaction (ORR) is crucial for metal-air batteries, in which Pt-based materials are the benchmark catalysts for ORR. However, the high cost and limited supplies of Pt limit its broad use in commercial applications. Designing highly efficient Pt electrocatalysts can reduce material cost and enable commercial success for a wide variety of electrochemical technologies. Herein, we prepared Pt/MnOx and Pt/MnO electrocatalysts via deposition-precipitation and H-2-reduction approaches. The Pt mass activities towards the ORR at 0.7 V for the Pt/MnOx, and Pt/MnO catalysts were 4.0 and 3.7 A mg(Pt)(-1), respectively, which were 20, and 18.5 times as commercial 20% Pt/C catalyst. The transferred electron numbers (n) were 3.6 and 4.0 for Pt/MnOx and Pt/MnO, respectively. Moreover, Pt/MnO catalyst exhibited a good ORR stability after 500 cycles compared to Pt/MnOx catalyst in 0.1 M KOH.
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CATALYSIS TODAY
ISSN: 0920-5861
Year: 2019
Volume: 332
Page: 101-108
5 . 3 0 0
JCR@2022
ESI Discipline: CHEMISTRY;
ESI HC Threshold:166
JCR Journal Grade:1
Cited Count:
WoS CC Cited Count: 34
SCOPUS Cited Count: 34
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 10
Affiliated Colleges: