An　electrochemical　oxidative　addition　of　sulfonamides　and　imide　to　allyl　sulfones　was　developed　for　the　facile　synthesis　of　synthetically　useful　allylamines.　This　method　avoids　the　use　of　transition　metal　catalysts　and　additional　bases,　which　are　commonly　used　for　the　synthesis　of　allylamines.　Moreover,　cheap　and　easily　available　NaI　was　employed　as　the　mediator　without　use　of　an　external　supporting　electrolyte.　Radical　trapping　experiments　showed　that　nitrogen-centered　radicals　were　involved　in　these　transformations.