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Author:

Liu, Xiaoxu (Liu, Xiaoxu.) | Li, Na (Li, Na.) | Yang, Chen (Yang, Chen.) | Liu, Zhen (Liu, Zhen.) | Feng, Yanqi (Feng, Yanqi.) | Dong, Wanmeng (Dong, Wanmeng.) | Liu, Shikun (Liu, Shikun.) | Liu, Hui (Liu, Hui.) | Jia, Yanlin (Jia, Yanlin.) | Zhao, Jiupeng (Zhao, Jiupeng.) | Li, Yao (Li, Yao.)

Indexed by:

EI Scopus SCIE

Abstract:

Nanoscale microstructure designing is playing an important role in improving the performance of electrode materials of an electrochemical battery. The Sn based anode is among the very high-capacity but less-stable materials, and has been used mostly for anode of the Li-ion battery with unsatisfactory performance. In this work, we design a new type of 3D porous graphene and nano-Sn composite (Sn/ Void@G) by simple one-step annealing of graphene oxide, polystyrene spheres and stannic chloride for both high performance Li- and Na-ion battery anodes. More importantly, the 3D porous graphene formed tunable micro-nano void as a highly efficient "bumper" to accommodate the large volume expansion of nano-Sn particles. As results, the discharge specific capacity of the Sn/Void@G, anode still remains 45.3% while the charge-discharge current is increased 50 times, and the capacity is more than 400 mAh g(-1) after 500 cycles at 5C rate. For Na storage, the integrated anodes deliver the Na storage capacity of 786.1 mAh/g at 0.1C rate and the capacity of more than 340 mAh/g after 800 cycles at 2C rate. The present result on Li and Na ion battery may pave the way to next generation high power and energy density batteries. (C) 2019 Elsevier B.V. All rights reserved.

Keyword:

Lithium ion battery Na-ion storage Sn anode High-performance 3D Porous graphene

Author Community:

  • [ 1 ] [Liu, Xiaoxu]Shaanxi Univ Sci & Technol, Sch Mat Sci & Engn, Shaanxi Key Lab Green Preparat & Functionalizat I, Xian 710021, Shaanxi, Peoples R China
  • [ 2 ] [Feng, Yanqi]Shaanxi Univ Sci & Technol, Sch Mat Sci & Engn, Shaanxi Key Lab Green Preparat & Functionalizat I, Xian 710021, Shaanxi, Peoples R China
  • [ 3 ] [Dong, Wanmeng]Shaanxi Univ Sci & Technol, Sch Mat Sci & Engn, Shaanxi Key Lab Green Preparat & Functionalizat I, Xian 710021, Shaanxi, Peoples R China
  • [ 4 ] [Liu, Hui]Shaanxi Univ Sci & Technol, Sch Mat Sci & Engn, Shaanxi Key Lab Green Preparat & Functionalizat I, Xian 710021, Shaanxi, Peoples R China
  • [ 5 ] [Liu, Shikun]Harbin Inst Technol, Sch Chem Engn & Technol, Harbin 150001, Heilongjiang, Peoples R China
  • [ 6 ] [Zhao, Jiupeng]Harbin Inst Technol, Sch Chem Engn & Technol, Harbin 150001, Heilongjiang, Peoples R China
  • [ 7 ] [Li, Yao]Harbin Inst Technol, Sch Chem Engn & Technol, Harbin 150001, Heilongjiang, Peoples R China
  • [ 8 ] [Li, Na]Heilongjiang Univ Sci & Technol, Harbin 150027, Heilongjiang, Peoples R China
  • [ 9 ] [Yang, Chen]Heilongjiang Univ Sci & Technol, Harbin 150027, Heilongjiang, Peoples R China
  • [ 10 ] [Liu, Zhen]Tech Univ Clausthal, Inst Electrochem, Arnold Sommerfeld Str 6, D-38678 Clausthal Zellerfeld, Germany
  • [ 11 ] [Jia, Yanlin]Cent S Univ, Coll Mat Sci & Engn, Changsha 410083, Hunan, Peoples R China
  • [ 12 ] [Jia, Yanlin]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 13 ] [Li, Yao]Harbin Inst Technol, Ctr Composite Mat, Harbin 150001, Heilongjiang, Peoples R China

Reprint Author's Address:

  • [Zhao, Jiupeng]Harbin Inst Technol, Sch Chem Engn & Technol, Harbin 150001, Heilongjiang, Peoples R China;;[Li, Yao]Harbin Inst Technol, Sch Chem Engn & Technol, Harbin 150001, Heilongjiang, Peoples R China;;[Jia, Yanlin]Cent S Univ, Coll Mat Sci & Engn, Changsha 410083, Hunan, Peoples R China

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Source :

JOURNAL OF ALLOYS AND COMPOUNDS

ISSN: 0925-8388

Year: 2019

Volume: 790

Page: 1043-1050

6 . 2 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:211

JCR Journal Grade:2

Cited Count:

WoS CC Cited Count: 22

SCOPUS Cited Count: 23

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 9

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