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Author:

Wang, Xin (Wang, Xin.) | Cui, Suping (Cui, Suping.) (Scholars:崔素萍) | Yan, Bilan (Yan, Bilan.) | Wang, Lan (Wang, Lan.) | Chen, Yanhe (Chen, Yanhe.) | Zhang, Jinshan (Zhang, Jinshan.)

Indexed by:

EI Scopus SCIE

Abstract:

The isothermal absorption properties and kinetic model of Cr (VI) and Cr (III) onto ettringite were investigated using the batch adsorption method. IR analysis was used to study the difference and mechanism of the adsorption of chromium ions with different valence states. The results show that the adsorption of Cr(III) onto ettringite at 20 degrees C agrees with Langmuir's isothermal model. The ion binding stability was significantly greater than that of Cr (VI). While the adsorption of Cr(VI) onto ettringite agrees with Freundlich's isothermal model, the D-R model fits the adsorption isotherms of two types of valence Cr (R-2> O.994). It can be concluded that the adsorption of Cr (III) onto ettringite is mainly by chemical adsorption and that the adsorption of Cr (VI) onto ettringite is mainly by physical adsorption. Dynamic model fitting and model parameter analyses show that the adsorption of Cr (III) onto ettringite agrees with the pseudo second order kinetics model given by Lagergren. The formation of chemical bonds is the main factor causing the fast adsorption. Cr (VI) adsorption is mainly dominated by liquid film diffusion, and the adsorption rate is much slower than that of Cr (III) adsorption.

Keyword:

mechanism Cr adsorption ettringite kinetics

Author Community:

  • [ 1 ] [Wang, Xin]Beijing Univ Technol, Sch Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Cui, Suping]Beijing Univ Technol, Sch Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Wang, Lan]Beijing Univ Technol, Sch Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Wang, Xin]China Bldg Mat Acad, State Key Lab Green Bldg Mat, Beijing 100024, Peoples R China
  • [ 5 ] [Yan, Bilan]China Bldg Mat Acad, State Key Lab Green Bldg Mat, Beijing 100024, Peoples R China
  • [ 6 ] [Chen, Yanhe]China Bldg Mat Acad, State Key Lab Green Bldg Mat, Beijing 100024, Peoples R China
  • [ 7 ] [Zhang, Jinshan]China Bldg Mat Acad, State Key Lab Green Bldg Mat, Beijing 100024, Peoples R China

Reprint Author's Address:

  • 崔素萍

    [Cui, Suping]Beijing Univ Technol, Sch Mat Sci & Engn, Beijing 100124, Peoples R China

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Source :

JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION

ISSN: 1000-2413

Year: 2019

Issue: 3

Volume: 34

Page: 587-595

1 . 6 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:211

JCR Journal Grade:4

Cited Count:

WoS CC Cited Count: 10

SCOPUS Cited Count: 10

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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