Indexed by:
Abstract:
The dispersion behaviors of multi-walled carbon nanotubes (MWCNTs) in water, using an ionic-gemini type molecule, 4, 4'-di (n-alkyl) diphenylmethane disulfate salt (C-n-DSDM, n = 12, 14, 16) as the dispersant, were investigated. The MWCNTs reinforced magnesium (Mg) matrix composite was fabricated successfully by using the MWCNTs dispersed by DSDM. The effects of hydrophobic chain length, sonication time and pH on the dispersibility of MWCNTs were characterized by UV-vis spectrophotometer, dynamic light scattering, Raman spectroscopy, transmission electron microscopy and zeta potential measurements. Results show that the C-n-DSDM can effectively disperse MWCNTs in water through a noncovalent functionalizing mechanism, and the dispersion is enhanced with reducing in the hydrophobic chain length, i.e. the C-12-DSDM shows the best dispersibility among the three kinds of C-n-DSDM. The pH value of water for the most effective dispersion is 7, and the dispersibility is improved with the increase in sonication time. The tensile test result of the C-12-DSDM dispersed MWCNTs reinforced Mg matrix composite demonstrates that the mechanical properties especially the elongation are outstandingly enhanced, i.e. by addition of 0.1 wt% C-12-DSDM dispersed MWCNTs, the ultimate tensile strength (UTS) and elongation (E) of pure Mg are improved by about 12.5% and 50.7%, respectively. The strengthening mechanism of C-12-DSDM-MWCNTs/Mg composite was discussed in detail.
Keyword:
Reprint Author's Address:
Email:
Source :
MATERIALS CHEMISTRY AND PHYSICS
ISSN: 0254-0584
Year: 2019
Volume: 229
Page: 279-285
4 . 6 0 0
JCR@2022
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:211
JCR Journal Grade:2
Cited Count:
WoS CC Cited Count: 8
SCOPUS Cited Count: 9
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2