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Author:

Yang, Kaixiang (Yang, Kaixiang.) | Yan, Zhengguang (Yan, Zhengguang.) | Ma, Lin (Ma, Lin.) | Du, Yiping (Du, Yiping.) | Peng, Bo (Peng, Bo.) | Feng, Jicun (Feng, Jicun.)

Indexed by:

Scopus SCIE PubMed

Abstract:

Cuprous oxide/silver (Cu2O/Ag) nanocomposites were prepared via a facile one-step method and used to construct an electrochemical sensor for hydrogen peroxide (H2O2) detection. In this method, AgNO3 and Cu(NO3)(2) were reduced to Cu2O/Ag nanocomposites by glucose in the presence of hexadecyl trimethyl ammonium bromide (CTAB) at a low temperature. The optimum condition was the molar ratio of silver nitrate and copper nitrate of 1:10, the temperature of 50 degrees C. Under this condition, Cu2O/Ag nanocomposites were obtained with uniformly distributed and tightly combined Cu2O and Ag nanoparticles. The size of Cu2O particles was less than 100 nm and that of Ag particles was less than 20 nm. Electrochemical experiments indicate that the Cu2O/Ag nanocomposites-based sensor possesses an excellent performance toward H2O2, showing a linear range of 0.2 to 4000 M, a high sensitivity of 87.0 A mM(-1) cm(-2), and a low detection limit of 0.2 M. The anti-interference capability experiments indicate this sensor has good selectivity toward H2O2. Additionally, the H2O2 recovery tests of the sensor in diluted milk solution signify its potential application in routine H2O2 analysis.

Keyword:

hydrogen peroxide cuprous oxide silver sensor electrochemistry nanocomposites

Author Community:

  • [ 1 ] [Yang, Kaixiang]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 2 ] [Yan, Zhengguang]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 3 ] [Ma, Lin]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 4 ] [Du, Yiping]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 5 ] [Peng, Bo]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 6 ] [Feng, Jicun]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 7 ] [Yang, Kaixiang]Beijing Univ Technol, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China
  • [ 8 ] [Yan, Zhengguang]Beijing Univ Technol, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China
  • [ 9 ] [Ma, Lin]Beijing Univ Technol, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China
  • [ 10 ] [Du, Yiping]Beijing Univ Technol, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China
  • [ 11 ] [Peng, Bo]Beijing Univ Technol, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China
  • [ 12 ] [Feng, Jicun]Beijing Univ Technol, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China

Reprint Author's Address:

  • [Yan, Zhengguang]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China;;[Yan, Zhengguang]Beijing Univ Technol, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China

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Source :

NANOMATERIALS

ISSN: 2079-4991

Year: 2019

Issue: 4

Volume: 9

5 . 3 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:211

JCR Journal Grade:2

Cited Count:

WoS CC Cited Count: 23

SCOPUS Cited Count: 24

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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