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Author:

Liu, Huan (Liu, Huan.) | Wang, Errui (Wang, Errui.) | Zhang, Qi (Zhang, Qi.) | Ren, Yibin (Ren, Yibin.) | Guo, Xianwei (Guo, Xianwei.) | Wang, Lin (Wang, Lin.) | Li, Guangyin (Li, Guangyin.) | Yu, Haijun (Yu, Haijun.) (Scholars:尉海军)

Indexed by:

EI Scopus SCIE

Abstract:

Lithium metal anode is considered one of the most promising anode materials for lithium rechargeable batteries due to its highest theoretical specific capacity and lowest anode potential. However, dendritic growth during Li planting leads a safety concern and hinders the application of lithium (Li) metal batteries. Herein, unique 3D nanoporous/macroporous structure conductive Cu was designed and used as the current collector for Li planting/stripping to regulate metal Li deposition and inhibit the growth of lithium dendrite. The nanoporous/macroporous Cu current collector can effectively reduce the local current density and guide the metallic Li nucleation, leading Li to deposit uniformly on its surface. As a result, the modified Li@ nanoporous/macroporous Cu current collector composite anode possesses a dendrite-free morphology and an enhanced cycling stability with a high average Coulombic efficiency of 98% for 400 h. When matching the LiFePO4 cathode, the LiFePO4 and Li@porous Cu current collector anode resultant full cell exhibits stable cycling performance.

Keyword:

Lithium metal anode Dendrite-free Lithium deposition Nanoporous/macroporous Cu Stable cycling performance

Author Community:

  • [ 1 ] [Liu, Huan]Beijing Univ Technol, Minist Educ, Key Lab Adv Funct Mat, Coll Mat Sci & Engn, Pingleyuan 100, Beijing 100124, Peoples R China
  • [ 2 ] [Wang, Errui]Beijing Univ Technol, Minist Educ, Key Lab Adv Funct Mat, Coll Mat Sci & Engn, Pingleyuan 100, Beijing 100124, Peoples R China
  • [ 3 ] [Zhang, Qi]Beijing Univ Technol, Minist Educ, Key Lab Adv Funct Mat, Coll Mat Sci & Engn, Pingleyuan 100, Beijing 100124, Peoples R China
  • [ 4 ] [Guo, Xianwei]Beijing Univ Technol, Minist Educ, Key Lab Adv Funct Mat, Coll Mat Sci & Engn, Pingleyuan 100, Beijing 100124, Peoples R China
  • [ 5 ] [Wang, Lin]Beijing Univ Technol, Minist Educ, Key Lab Adv Funct Mat, Coll Mat Sci & Engn, Pingleyuan 100, Beijing 100124, Peoples R China
  • [ 6 ] [Li, Guangyin]Beijing Univ Technol, Minist Educ, Key Lab Adv Funct Mat, Coll Mat Sci & Engn, Pingleyuan 100, Beijing 100124, Peoples R China
  • [ 7 ] [Yu, Haijun]Beijing Univ Technol, Minist Educ, Key Lab Adv Funct Mat, Coll Mat Sci & Engn, Pingleyuan 100, Beijing 100124, Peoples R China
  • [ 8 ] [Ren, Yibin]Chinese Acad Sci, Inst Met Res, Specialized Mat & Device Div, Shenyang 110016, Liaoning, Peoples R China

Reprint Author's Address:

  • 尉海军

    [Yu, Haijun]Beijing Univ Technol, Minist Educ, Key Lab Adv Funct Mat, Coll Mat Sci & Engn, Pingleyuan 100, Beijing 100124, Peoples R China

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Source :

ENERGY STORAGE MATERIALS

ISSN: 2405-8297

Year: 2019

Volume: 17

Page: 253-259

2 0 . 4 0 0

JCR@2022

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count: 122

SCOPUS Cited Count: 121

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 11

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