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Author:

Liang, Q. (Liang, Q..) | Liang, W. (Liang, W..) | Fan, X. (Fan, X..) | Song, L. (Song, L..) | Li, J. (Li, J..) (Scholars:李坚) | He, H. (He, H..) (Scholars:何洪)

Indexed by:

Scopus PKU CSCD

Abstract:

The effects of V2O5 loading, the volume fractions of O2, NO, SO2 and H2O, n(NH3)/n(NO), gas hourly space velocity and online heat regeneration on NO conversion of V2O5-WO3/TiO2 catalyst prepared by impregnation method were investigated. Combined with the experimental results, 3% V2O5 was selected as the optimal loading, and NO conversion of 3% V2O5-WO3/TiO2 catalyst was 93.7% at 160 ℃. The selectivity of N2 was more than 98% and SO2 oxidation was less than 1% in the range of 110-320 ℃. NO conversion of catalyst increased with the increase of the volume fraction of O2, and decreased with the increase of the volume fraction of NO, however, the NOx removal amount gradually increased. When n(NH3)/n(NO)≤1, the optimal activity of catalyst equalled the respective n(NH3)/n(NO), and when n(NH3)/n(NO)>1, the activity was barely improved. With the increase of the space velocity, the high activity temperature range of the catalyst was narrowed, and the activity decreased in varying degrees. The characterization results show that the morphology of catalyst is blurred and the surface covered with irregular flocs, specific surface area and pore volume decrease in different degrees, and tiny pores are preferred to be blocked after selective catalytic reduction (SCR) reaction containing SO2 and H2O. The contents of V2O5 are reduced 0.98% and WO3 reduced 1.6%, the side reaction products include NH4 + and SO4 2-. During the process of online heat regeneration, catalyst delayed the decomposition of ammonium sulfate, which caused the catalyst's resistance to poisoning to be worse and the activity was difficult to be recover. © 2019, Editorial Department of Journal of Beijing University of Technology. All right reserved.

Keyword:

Different flue gas conditions; Low temperature SCR; Non electric power industry; Online heat regeneration; V2O5-WO3/TiO2

Author Community:

  • [ 1 ] [Liang, Q.]Key Laboratory of Beijing on Regional Air Pollution Control, Beijing university of Technology, Beijing, 100124, China
  • [ 2 ] [Liang, Q.]Beijing Key Laboratory for Green Catalysis and Separation, Beijing university of Technology, Beijing, 100124, China
  • [ 3 ] [Liang, Q.]Beijing Municipal Institute of Labor Protection, Beijing, 100054, China
  • [ 4 ] [Liang, W.]Key Laboratory of Beijing on Regional Air Pollution Control, Beijing university of Technology, Beijing, 100124, China
  • [ 5 ] [Liang, W.]Beijing Key Laboratory for Green Catalysis and Separation, Beijing university of Technology, Beijing, 100124, China
  • [ 6 ] [Fan, X.]Key Laboratory of Beijing on Regional Air Pollution Control, Beijing university of Technology, Beijing, 100124, China
  • [ 7 ] [Fan, X.]Beijing Key Laboratory for Green Catalysis and Separation, Beijing university of Technology, Beijing, 100124, China
  • [ 8 ] [Song, L.]Key Laboratory of Beijing on Regional Air Pollution Control, Beijing university of Technology, Beijing, 100124, China
  • [ 9 ] [Song, L.]Beijing Key Laboratory for Green Catalysis and Separation, Beijing university of Technology, Beijing, 100124, China
  • [ 10 ] [Li, J.]Key Laboratory of Beijing on Regional Air Pollution Control, Beijing university of Technology, Beijing, 100124, China
  • [ 11 ] [Li, J.]Beijing Key Laboratory for Green Catalysis and Separation, Beijing university of Technology, Beijing, 100124, China
  • [ 12 ] [He, H.]Key Laboratory of Beijing on Regional Air Pollution Control, Beijing university of Technology, Beijing, 100124, China
  • [ 13 ] [He, H.]Beijing Key Laboratory for Green Catalysis and Separation, Beijing university of Technology, Beijing, 100124, China

Reprint Author's Address:

  • 李坚

    [Li, J.]Key Laboratory of Beijing on Regional Air Pollution Control, Beijing university of TechnologyChina

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Source :

Journal of Beijing University of Technology

ISSN: 0254-0037

Year: 2019

Issue: 7

Volume: 45

Page: 699-709

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 10

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