In　industrial　manufacturing,　alloying　can　contribute　to　the　passivation　of　active　metals　and　markedly　improve　their　corrosion　resistance.　This　inspires　us　to　solve　the　current　critical　problem　of　Ag　nanowires　(Ag　NWs)　that　have　poor　stability　against　chemical　and　electrochemical　corrosion.　These　problems　have　seriously　limited　the　applications　of　Ag　NWs　in　optoelectronic　devices　where　they　are　used　for　transparent　conductive　electrodes.　Here,　a　kind　of　transparent　conductive　electrode　based　on　Ag@　Pt　alloy-walled　hollow　nanowires　(Ag@Pt　AHNWs)　is　successfully　fabricated　by　introducing　12　mol　%　Pt　into　long　Ag　NWs　to　form　Ag@Pt　alloy.　The　as　synthesized　electrodes　exhibit　better　optical　transmittance　(82%　at　the　wavelength　of　550　nm)　under　high　electrical　conductivity　(28.73　Omega/sq(-1)),　high　thermal　stability　up　to　400　degrees　C　for　11　h,　and　remarkable　mechanical　flexibility　(remaining　stable　after　5000　cycles　bending),　as　well　as　high　resistance　against　chemical　and　electrochemical　corrosion.　The　Ag@Pt　AHNWs　electrodes　are　further　applied　in　a　primary　bifunctional　polyaniline　electrochemical　device,　and　the　device　shows　promising　flexibility,　noticeable　multicolor　performances,　and　high　specific　capacitance　because　of　the　remarkable　mechanical　flexibility　and　electrochemical　stability　of　Ag@Pt　AHNWs.　This　work　will　provide　an　optional　approach　for　the　preparation　of　other　metal　nanomaterial　electrodes　with　high　stability.