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Spinel Co3O4, as conversion-type transitional metal oxide, has attracted extensive interest for LIBs anode due to its high theoretical capacity. The application of transitional metal oxide including Co3O4 anode has been proved challenging due to voltage hysteresis, bad rate capability, extremely low initial Coulombic efficiency (typically 65 similar to 70%), and volume change induced mechanical failure. Among the facing problems, the fundamental understanding of severe capacity fading at high C-rate is clearly needed to be unveiled. In this paper, we utilized in situ transmission electron microscopy (TEM) to study the electrochemical reaction process of spinel Co3O4 anode and firstly unveiled the rate-dependent morphological and structural evolution process. It has been demonstrated that the structural evolution from pristine Co3O4 phase to the formation of Co/Li2O composites during lithiation (bias =similar to 3 V). Impressively, the Co/Li2O composites could fully delithiated into pure tightly-contacted CoO crystals (similar to 1.45 nm) at lower delithiated bias (+3 V); while the lithiated products partially transformed into the CoO crystals, and further suffered a severe aggregation (similar to 6 nm) at higher delithiated bias (+8 V). These findings advance the understanding of the mechanism of capacity fading at high current density (C-rate) in conversion-type spinel Co3O4 anode for lithium ion batteries. (C) 2018 Elsevier B.V. All rights reserved.
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JOURNAL OF ALLOYS AND COMPOUNDS
ISSN: 0925-8388
Year: 2018
Volume: 763
Page: 349-354
6 . 2 0 0
JCR@2022
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:260
JCR Journal Grade:1
Cited Count:
WoS CC Cited Count: 7
SCOPUS Cited Count: 7
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 12
Affiliated Colleges: