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Author:

Xu, XiaoLong (Xu, XiaoLong.) | Wang, Hao (Wang, Hao.) (Scholars:汪浩) | Xie, YiZhu (Xie, YiZhu.) | Liu, JingBing (Liu, JingBing.) | Yan, Hui (Yan, Hui.) | Liu, Wei (Liu, Wei.)

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EI Scopus SCIE

Abstract:

Electrode stability has been an important parameter in energy conversion and storage devices. However, many of these electrodes suffer from irreversible degradation, for example, irreversible sulfation in the negative electrode of lead acid battery (LAB) and lithium dendrite on the anode surface of lithium ion battery (LIB). We here report a facile synthesis approach of graphitized mesoporous carbons (GMCs), which derived from zeolitic imidazolate frameworks-8 (ZIF-8) via controlling the annealing parameters, as porous media in the electrodes for suppressing the irreversible sulfation and the dendritic lithium formation. GMC additive in the negative electrode of LAB effectively retards the irreversible sulfation by controlling the growing size of PbSO4 crystal particles. The cycle life of LAB extends 8.5 times after being added GMC additive. Dendrite growth in LIBs is suppressed obviously because GMCs control the lithium growth along the mesoporous structure and the particle voids of GMCs, resulting in the significant extension of operation time of the LIB without a short circuit. The capacity retention of Li and Li/GMC anodes are 42.3% and 90.1%, respectively, at 0.5 C after 200 cycles. The work reveals a facile but efficient synthesis approach of additive to extend the cycle life of LABs and LIBs. (C) 2018 The Electrochemical Society.

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Author Community:

  • [ 1 ] [Xu, XiaoLong]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Wang, Hao]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Liu, JingBing]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Yan, Hui]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Xie, YiZhu]Shenzhen Univ, Coll Phys & Energy, Shenzhen Key Lab Adv Thin Films & Applicat, Shenzhen 518060, Peoples R China
  • [ 6 ] [Liu, Wei]State Grid Corp China, State Grid Anhui Elect Power Res Inst, Key Lab Sulfur Hexafluoride Gas Anal & Purificat, Hefei 230022, Anhui, Peoples R China

Reprint Author's Address:

  • 汪浩

    [Wang, Hao]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China;;[Xie, YiZhu]Shenzhen Univ, Coll Phys & Energy, Shenzhen Key Lab Adv Thin Films & Applicat, Shenzhen 518060, Peoples R China

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Source :

JOURNAL OF THE ELECTROCHEMICAL SOCIETY

ISSN: 0013-4651

Year: 2018

Issue: 13

Volume: 165

Page: A2978-A2984

3 . 9 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:192

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count: 11

SCOPUS Cited Count: 12

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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